On the problems of creating shells of fuel rods from zirconium alloys for tolerant fuel

A. A. Yakushkin, As “Src Rf Triniti”
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Abstract

Three directions of the establishment of accident tolerant fuel cladding for light water reactors are actively exploring at present: 1) replacement zirconium alloy E110 for more corrosion-resistant material in accident operation conditions; 2) surface dispersion hardening or doping of the zirconium cladding of fuel element; 3) deposition a corrosion-resistant coating to the fuel cladding. The first direction requires significant and irreversible changes in fuel rod production technology and has long-term prospects. Conversely, the second direction suggest minimal changes in the fuel rod production technology, however, it has no significant effect on the high temperature oxidation kinetics of fuel claddings in steam. Using of a corrosion resistant coating results in a significant change in the high temperature oxidation kinetics of the zirconium alloy, (no transition to linear oxidation) that is related to maintaining the continuity of the oxide layer formed during oxidation. The issue provides a brief overview of the current state of research in the field of fuel, tolerant to the effects of coolant in emergency situations.
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耐受性燃料用锆合金制燃料棒壳的若干问题
目前,轻水堆耐事故燃料包壳的建立有三个方向正在积极探索:1)在事故运行条件下,用更耐腐蚀的材料替代锆合金E110;2)燃料元件锆包层表面分散硬化或掺杂;3)在燃料包壳上沉积一层耐腐蚀涂层。第一个方向需要燃料棒生产技术发生重大且不可逆转的变化,并且具有长期前景。相反,第二个方向表明燃料棒生产技术的变化很小,但是,它对蒸汽中燃料包壳的高温氧化动力学没有显著影响。使用耐腐蚀涂层会导致锆合金的高温氧化动力学发生显著变化(不向线性氧化过渡),这与保持氧化过程中形成的氧化层的连续性有关。本刊简要概述了在紧急情况下可容忍冷却剂影响的燃料领域的研究现状。
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