Contemporary approaches to reducing scale formation in heat-exchange equipment

V. Golovin, S. A. Tyurina, V. A. Shchelkov
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Abstract

Objectives. Scale formation and corrosion are serious problems for heat and power equipment. These processes, when intense, can completely block the operation of the system, accelerating corrosion and leading to clogging, local overheating, and burnouts and ruptures of boilers and pipes, which in turn can lead to major environmental problems. Therefore, protecting surfaces from scale formation and corrosion is an important task. Promising methods for preventing the development of undesirable consequences include changing the composition of polymer coatings, e.g., by introducing microencapsulated corrosion inhibitors, as well as surface modification approaches, such as hydrophobization of the polymer coating surface. The purpose of the present work is to analyze methods for reducing scale formation and the rate of corrosion processes, as well as to study the efficiency of modification of paints and coatings by introducing microencapsulated corrosion inhibitors.Methods. The study was based on the use of accelerated corrosion tests.Results. Existing methods for reducing scale formation and corrosion rate on the surfaces of heat and power equipment were analyzed. The efficiency of modifying protective polymer materials by introducing microcapsules containing an active phosphonate additive was compared with approaches involving the surface modification of such protective materials.Conclusions. It was determined that the modification of paints and coatings by introducing microencapsulated active additives can significantly reduce the rates of both scale formation and corrosion. By implementing stateof-the-art methods for modifying polymer coatings, a new generation of agents for efficiently preventing scale formation and corrosion processes can be developed for maintaining the high performance of heat-exchange equipment.
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减少换热设备中结垢的现代方法
目标。结垢和腐蚀是热电设备面临的严重问题。当这些过程强度大时,会完全阻断系统的运行,加速腐蚀并导致堵塞、局部过热、锅炉和管道烧坏和破裂,进而导致严重的环境问题。因此,保护表面免受结垢和腐蚀是一项重要的任务。为了防止不良后果的发展,有希望的方法包括改变聚合物涂层的组成,例如通过引入微封装的腐蚀抑制剂,以及表面改性方法,例如聚合物涂层表面的疏水性。本工作的目的是分析减少结垢和腐蚀过程速度的方法,并研究引入微囊化缓蚀剂对油漆和涂料的改性效率。这项研究是基于使用加速腐蚀试验的结果。分析了现有的减少热电设备表面结垢和腐蚀速度的方法。通过引入含有活性膦酸盐添加剂的微胶囊改性高分子防护材料,比较了改性高分子防护材料的效果。结果表明,通过引入微胶囊化活性添加剂对油漆和涂料进行改性,可以显著降低结垢率和腐蚀率。通过实施最先进的改性聚合物涂层的方法,可以开发新一代有效防止结垢和腐蚀过程的剂,以保持热交换设备的高性能。
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