{"title":"Relaxation of the CH2 Stretching Modes of Liquid Dihalomethanes","authors":"G. Seifert, M. Bartel, H. Graener","doi":"10.2174/1874067700802010022","DOIUrl":null,"url":null,"abstract":"The vibrational relaxation of the liquid dihalomethanes CH2I2, CH2Br2 and CH2Cl2 has been studied by a com- bination of IR/IR and IR/Raman pump-probe techniques applying a time resolution of ~2 ps. Careful analysis of the re- sults shows a general trend of decreasing relaxation rates from dichloromethane to diiodomethane, with few individual deviations. Possible explanations for these observations are discussed.","PeriodicalId":250297,"journal":{"name":"The Open Physical Chemistry Journal","volume":"109 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2008-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Physical Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874067700802010022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
The vibrational relaxation of the liquid dihalomethanes CH2I2, CH2Br2 and CH2Cl2 has been studied by a com- bination of IR/IR and IR/Raman pump-probe techniques applying a time resolution of ~2 ps. Careful analysis of the re- sults shows a general trend of decreasing relaxation rates from dichloromethane to diiodomethane, with few individual deviations. Possible explanations for these observations are discussed.
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