Martin H. Jones , William Levason , Charles A. McAuliffe , Stephen G. Murray , Denise M. Johns
{"title":"The relationship of some copper (II) complexes of facultative tetrathioethers to the coordination environment in the “blue” copper proteins","authors":"Martin H. Jones , William Levason , Charles A. McAuliffe , Stephen G. Murray , Denise M. Johns","doi":"10.1016/S0006-3061(00)80194-5","DOIUrl":null,"url":null,"abstract":"<div><p>The facultative potentially tetradentate thioether ligands 1,2-bis(2-methylthioethylthio)ethane (2,2,2), 1,3-bis(2-methylthioethylthio)propane (2,3,2) and 1,2-bis(3-methylthiopropylthio)ethane (3,2,3) react with copper(II) salts to form Cu<sub>2</sub>(2,2,2)Cl<sub>4</sub>, Cu<sub>3</sub>(ligand)X<sub>6</sub> (ligand = 2,3,2 and 3,2,3 X = Cl; ligand = 2,2,2 2,3,2 and 3,2,3 X = Br), and Cu(ligand)(ClO<sub>4</sub>)<sub>2</sub>. The stoichiom-</p></div>","PeriodicalId":9177,"journal":{"name":"Bioinorganic chemistry","volume":"8 3","pages":"Pages 201-213"},"PeriodicalIF":0.0000,"publicationDate":"1978-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0006-3061(00)80194-5","citationCount":"57","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bioinorganic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0006306100801945","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 57
Abstract
The facultative potentially tetradentate thioether ligands 1,2-bis(2-methylthioethylthio)ethane (2,2,2), 1,3-bis(2-methylthioethylthio)propane (2,3,2) and 1,2-bis(3-methylthiopropylthio)ethane (3,2,3) react with copper(II) salts to form Cu2(2,2,2)Cl4, Cu3(ligand)X6 (ligand = 2,3,2 and 3,2,3 X = Cl; ligand = 2,2,2 2,3,2 and 3,2,3 X = Br), and Cu(ligand)(ClO4)2. The stoichiom-
兼性潜在的四牙齿硫醚配体1,2-二(2-甲基硫乙基硫)乙烷(2,2,2)、1,3-二(2-甲基硫乙基硫)丙烷(2,3,2)和1,2-二(3-甲基硫丙基硫)乙烷(3,2,3)与铜(II)盐反应生成Cu2(2,2,2)Cl4、Cu3(配体)X6(配体= 2,3,2和3,2,3 X = Cl;配体= 2,2,2,3,2和3,2,3 X = Br)和Cu(配体)(ClO4)2。stoichiom -
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