Confined Evaporation-Mediated Enhanced Residence Time of Levitated Water Drops over Deep Oil Pools

IF 3.7 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2021-11-16 DOI:10.1021/acs.langmuir.1c02443
Naveen Puthussery Thrivikraman, Ashish Khare, Amit Sanjay Hegde, Anilakkad Raman Harikrishnan*
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引用次数: 6

Abstract

We observe the impact of bouncing and floating of water drops on a pool of immiscible volatile oil pools at low Weber numbers. The residence time of the impacting drop ranges from a few milliseconds to a few seconds before it sinks into the lighter oil phase. It is hypothesized that the confined evaporation from the volatile oil pool replenishes the thin film draining and results in prolonged floating and delayed sinking of drops into the oil pool. Water drops are released from a low height to impact on volatile hydrocarbon oil deep pools of various volatilities. The floating dynamics and residence times are captured using high-speed imaging. A theoretical model for the residence time has been developed to evaluate the hypothesis. The drop residence time is found to be directly proportional to the volatility of the oil pool in accordance with the hypothesis. The mathematical model incorporating the coupled confined evaporation and film draining dynamics is found to be in well agreement with the experimentally observed residence time. The bouncing–sinking regime map has been developed based on the experimental data.

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密闭蒸发介导的深层油藏悬浮水滴停留时间的延长
我们观察了在低韦伯数条件下,水滴在不混相挥发油池上的弹跳和漂浮的影响。撞击液滴的停留时间从几毫秒到几秒钟不等,然后它就沉入了较轻的油相。假设挥发性油池的密闭蒸发补充了薄膜排水,导致液滴在油池中漂浮时间延长,下沉时间延迟。水滴从低高度释放,冲击不同挥发性的挥发性烃油深池。浮动动态和停留时间使用高速成像捕获。为了验证这一假设,建立了一个停留时间的理论模型。根据假设,发现液滴停留时间与油藏的波动率成正比。结果表明,结合密闭蒸发和膜层排水耦合动力学的数学模型与实验观测的停留时间吻合较好。在实验数据的基础上,建立了弹跳-下沉状态图。
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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