An experimental and computer simulation study of the role of CdS in CIS-type solar cells

J. Hou, S. Fonash, J. Kessler
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引用次数: 3

Abstract

An experimental and computer simulation study of the "red kink" current-voltage features seen in many CdS/Cu(In,Ga)Se/sub 2/ solar cells has been undertaken to gain more insight into cell operation and to address the controversy over the role of the CdS layer. The study shows that in structures with chemical bath deposited CdS: (1) the "red kink" effect is due to a low free electron concentration and high trap state concentration in the CdS layer, (2) the direct cause of the "red kink" is current modulated free electron concentration in the CdS, and (3) under white light the positive space charge built-up in CdS traps greatly enhances the photo-carrier collecting electric field in the absorber layer. Therefore, the CdS layer has an important role in the junction under white light.
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CdS在cis型太阳能电池中作用的实验和计算机模拟研究
对许多CdS/Cu(in,Ga)Se/sub 2/太阳能电池中的“红结”电流-电压特征进行了实验和计算机模拟研究,以获得对电池操作的更多见解,并解决关于CdS层作用的争议。研究表明,在化学浴沉积的CdS结构中:(1)“红结”效应是由于CdS层中自由电子浓度低而陷阱态浓度高,(2)“红结”效应的直接原因是CdS中电流调制的自由电子浓度,(3)在白光下,CdS陷阱中积累的正空间电荷大大增强了吸收层中的光载流子收集电场。因此,CdS层在白光下的结中起着重要的作用。
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