Characterization of polybutene modified denture acrylics

B. Balzli, A. Puckett, A. McKie, D. Pettrey
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Abstract

Summary form only received as follows: The objective of this study was to evaluate the use of a polybutene additive to improve the flexure strength of cold cured acrylic systems. Three different number average molecular weight polybutenes were used including H100 (920 g/mole), L65 (610 g/mole) and L14 (320 g/mole) (Amoco Chemical Co.). The polybutenes were blended at 0, 1, 5 and 10 weight % with a cold cure acrylic system and compression molded into rectangular specimens 13 mm wide x 3 mm thick x 28 mm long. Ten specimens were prepared for each formulation and stored for seven days in distilled water at 37/spl deg/C before flexure testing. A three point flexure test was run using a span of 20 mm at a rate of 1 mm/minute. The results for the cold cure acrylic are given. The only polybutene formulation which improved the flexure strength was the 1% H100 composition. Although the 1% H100 formulations did improve the flexure strength of the acrylic, the change was not statistically significant when compared using a t-test (p <.05). Incorporation of polybutenes did not significantly improve the flexure strength of dental acrylics tested in this study.
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聚丁烯改性义齿丙烯酸树脂的表征
本研究的目的是评估使用聚丁烯添加剂来提高冷固化丙烯酸体系的抗弯强度。采用三种不同数平均分子量的聚丁烯,分别为H100 (920 g/mol)、L65 (610 g/mol)和L14 (320 g/mol) (Amoco Chemical Co.)。将聚丁烯以0、1、5和10%的重量与冷固化丙烯酸系统混合,并压缩成13毫米宽x 3毫米厚x 28毫米长的矩形样品。每个配方制备10个样品,在37℃的蒸馏水中保存7天,然后进行弯曲试验。以1毫米/分钟的速度,使用20毫米的跨度进行三点弯曲试验。给出了冷固化亚克力的实验结果。唯一提高抗弯强度的聚丁烯配方是1% H100组成。虽然1% H100配方确实提高了丙烯酸的抗弯强度,但使用t检验比较时,变化无统计学意义(p < 0.05)。在本研究中,聚丁烯的掺入并没有显著提高牙科丙烯酸树脂的弯曲强度。
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