Design and fabrication of photonic devices based on colloidal nanocrystals

L. Martiradonna, A. Qualtieri, T. Stomeo, R. Cingolani, M. de Vittorio
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Abstract

Thanks to their low fabrication costs and the well established surface-functionalization techniques which allow their merging into a wide range of materials, wet-chemical synthesized colloidal nanocrystals are finding broad application in several fields, from pharmacology to cosmetics, food industry, textiles, optics and so on. In particular, semiconductor nanocrystals are widely exploited as quantum optical emitters, showing very high quantum yield (close to unity), stability, low tendency to photobleaching and possibility to be tuned from ultraviolet to infrared range. The realization of high performing photonic devices based on this class of emitters is therefore an extremely intriguing challenge; on the other hand, the best way to manipulate these emitters and integrate them in solid matrices, without dramatically decreasing their optical properties, is still under debate. Here we present a method for the fabrication of the main building blocks of photonic circuits by exploiting the localization of colloidal nanocrystals dispersed in polymeric matrices through lithographic techniques. The realization of waveguide structures, suspended stripes and photonic crystal nanocavities is shown as a demonstration of this approach.
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基于胶体纳米晶体的光子器件的设计与制造
由于其低廉的制造成本和完善的表面功能化技术,使其能够融合到广泛的材料中,湿化学合成的胶体纳米晶体在药理学、化妆品、食品工业、纺织、光学等多个领域得到了广泛的应用。特别是,半导体纳米晶体被广泛用作量子光发射体,具有非常高的量子产率(接近统一)、稳定性、低光漂白倾向和从紫外到红外范围调谐的可能性。因此,基于这类发射器的高性能光子器件的实现是一个非常有趣的挑战;另一方面,操纵这些发射器并将其集成到固体矩阵中,而不显著降低其光学特性的最佳方法仍在争论中。在这里,我们提出了一种通过光刻技术利用分散在聚合物基质中的胶体纳米晶体的局部化来制造光子电路的主要构件的方法。波导结构、悬浮条纹和光子晶体纳米腔的实现证明了这种方法。
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