Design And Researching Conductive Hybrid Biopolymer Nanocomposite Materials For Micro-And Nanoelectronics

V. Lebedev, D. Miroshnichenko, D. Bilets, Tetyana Tykhomyrova, O. Tsereniuk, Natalia Kry gina
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Abstract

In this article, new conductive hybrid biopolymer nanocomposites based on polylactid and humic substances were developed and studied. It has been established that humic substances, which were obtained from brown coals by extraction method, are characterized by nano dispersion in the range of 52–380 nm. It was found that due to the presence of a large number of active functional groups on the surface of such nanoparticles of humic substances is a hybrid modification of polylactid by the mechanism of template synthesis, which is accompanied by an increase in the degree of crystallization and the formation of a more rigid polymer structure, which allows to obtain hybrid biopolymer nanocomposites with significant impact strength and breaking stress during bending. It was also found that the obtained hybrid biopolymer nanocomposites based on polylactid and humic substances are characterized by levels at the value of resistance from 25 to 31 Ω sq−1. It is concluded that the designed hybrid biopolymer nanocomposites based on polylactide and humic substances in terms of their strength properties and complex of spectral-electrical characteristics are a promising basis for obtaining polymer matrices and materials for micro- and nanoelectronics.
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微纳电子学用导电杂化生物聚合物纳米复合材料的设计与研究
本文研究了基于聚乳酸和腐殖质的新型导电杂化生物聚合物纳米复合材料。从褐煤中萃取得到的腐殖质在52 ~ 380 nm范围内具有纳米分散特性。研究发现,由于这种腐殖质纳米颗粒表面存在大量的活性官能团,通过模板合成的机制对聚乳酸进行杂化改性,同时结晶程度增加,形成更加刚性的聚合物结构,从而获得具有显著冲击强度和弯曲断裂应力的杂化生物聚合物纳米复合材料。研究还发现,所获得的基于聚乳酸和腐殖质的杂化生物聚合物纳米复合材料的电阻值为25 ~ 31 Ω sq−1。结果表明,所设计的以聚丙交酯和腐殖质为基础的杂化生物聚合物纳米复合材料在强度性能和谱电特性复合方面具有良好的基础,为获得聚合物基质和微纳米电子材料提供了良好的基础。
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