Aspects of Creating Multilayer Coatings by Plasma Spraying

F. Panteleenko, V. Okovity, O. S. Devoino, A. A. Litvinko, V. V. Okovity, V. Astashinsky, V. M. Blumenstein
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Abstract

In the work, taking into account the state of the issue in the field of applying multilayer heat-shielding and wear-resistant coatings, directions of research are substantiated. The objectives of the development are: improvement of powder materials containing zirconium dioxide partially stabilized with yttrium oxide for plasma deposition of heat-shielding coa-tings; improvement of powder materials containing oxide ceramics and nickel-based alloys for plasma deposition of wear-resistant coatings; development of technological parameters of plasma spraying and subsequent processing by the effects of compression plasma on the coating; analysis of the quality of protective coatings obtained using the optimal technology by studying their structure and physical and mechanical properties. The ZrO2 – 7 % Y2O3 particles contain the predominant tetragonal Y0.15Zr0.85O0.93 phase, monoclinic and cubic ZrO2 phases, and the Al2O3–TiO2–Ni–Cr–Al–Y–Ta composition contains the Cr1.12Ni2.88 phase of the nickel-based solid solution, the a-Al2O3, g-Al2O3 phases, and the orthorhombic phase of titanium oxide TiO2 that contribute to its wear resistance. subsequent optimization of technological parameters for the process of plasma spraying of multilayer heat-shielding and wear-resistant coatings. Technological parameters for the process of plasma spraying of multi-layer heat-shielding and wear-resistant coatings are investigated with subsequent optimization. The optimization criteria were the utilization factor of the sprayed powder material and the structure of the coatings. The influence of the spraying distance on the values of operational characteristics of the formed plasma coatings on Al2O3–TiO2–Ni–Cr–Al–Y–Ta has been studied. The obtained results of controlling the phase composition of coatings by varying the chemical composition of powder materials are presented. In the process of deposition, the differences in the phase composition of the formed material are the more significant, the more inhomogeneous the distribution of elements in the initial powder material. Tests have been carried out for cyclic testing in an oven at a maximum temperature within 1300 °C of heat-shielding coatings to determine their heat resistance. They proved the influence of the phase composition of the formed coatings on their ability to withstand high-temperature oxidation.
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等离子喷涂制备多层涂层的几个方面
在工作中,结合多层热屏蔽耐磨涂层应用领域的现状,提出了今后的研究方向。开发的目标是:改进含有氧化钇部分稳定的二氧化锆的粉末材料,用于等离子沉积热屏蔽涂层;含氧化物陶瓷和镍基合金粉末材料等离子沉积耐磨涂层的改进利用压缩等离子体对涂层的影响制定等离子喷涂工艺参数及后续处理通过对涂层结构和物理力学性能的研究,分析了采用最佳工艺得到的防护涂层的质量。ZrO2 - 7% Y2O3颗粒主要由Y0.15Zr0.85O0.93四方相、单斜相和立方相组成,Al2O3-TiO2-Ni-Cr-Al-Y-Ta组成,主要由镍基固溶体的Cr1.12Ni2.88相、a-Al2O3、g-Al2O3相和氧化钛TiO2的正交相组成,这些组成有助于提高其耐磨性。多层热屏蔽耐磨涂层等离子喷涂工艺参数的后续优化。对多层隔热耐磨涂层的等离子喷涂工艺参数进行了研究,并进行了优化。优化标准为喷涂粉末材料的利用率和涂层的结构。研究了喷涂距离对Al2O3-TiO2-Ni-Cr-Al-Y-Ta等离子体涂层性能的影响。介绍了通过改变粉末材料的化学成分来控制涂层相组成的研究结果。在沉积过程中,形成的材料相组成差异越显著,初始粉末材料中元素分布越不均匀。在最高温度在1300°C以内的烘箱中对热屏蔽涂层进行了循环试验,以确定其耐热性。他们证明了所形成的涂层的相组成对其耐高温氧化能力的影响。
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