Structure and thermoelectric properties of nano-crystalline Rex-Si1-x thin film composites

A. Burkov, A. Heinrich, C. Gladun, W. Pitschke, J. Schumann
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Abstract

In this report results on phase formation and transport properties of amorphous and nano-crystalline Re-Si thin films are presented. The results imply that the partially crystallized Re-Si films, i.e. films consisting of amorphous and nano-crystalline phases form a new class of heterostructures which are essentially different from binary insulator-metal mixtures. We have found that the resistivity and thermopower of the heterogeneous films consisting of amorphous and nano-crystalline phases do not follow the well known effective medium approximation when the ratio between these two phases is varied. Both phase composition and crystalline grain size appear to be important parameters for the thermoelectric material optimization.
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纳米晶Rex-Si1-x薄膜复合材料的结构和热电性能
本文介绍了非晶和纳米晶Re-Si薄膜的相形成和输运特性。结果表明,部分结晶的Re-Si薄膜,即由非晶相和纳米晶相组成的薄膜,形成了一类新的异质结构,与二元绝缘体-金属混合物有本质的不同。我们发现,当非晶相和纳米晶相组成的非均相薄膜的电阻率和热功率不遵循已知的有效介质近似时,这两相之间的比例是不同的。相组成和晶粒尺寸都是热电材料优化的重要参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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