Thermoelectric properties of Bi/sub 2/Te/sub 3/-related materials prepared by pulse-current hot-pressing

H. Kitagawa, Y. Shinohara, T. Kitamura, Y. Noda
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Abstract

Hot-press deformation was performed for Bi/sub 2/Te/sub 3/-related samples. The ingots as the source material were grown by the Bridgman method with the nominal compositions of Bi/sub 0.5/Sb/sub 1.5/Te/sub 3/ and Bi/sub 2/Te/sub 2.85/Se/sub 0.15/ A disk cut from the ingot was deformed by hot-pressing under pulse-current heating. The crystal structures of the deformed samples were identified by X-ray diffraction. All diffraction peaks were assigned to Bi/sub 2/Te/sub 3/-type structure and the patterns indicate the samples were oriented in the hexagonal (00/spl middot/l) plane. The Hall effect measurements indicate that the carrier concentration of the samples is in the order of magnitude of 10/sup 25/ m/sup -3/ in the temperature range of 80 to 300 K. The power factor after the deformation exceeds those for the source ingots. The results indicate that the hot-press deformation can be expected to enhance thermoelectric properties of Bi/sub 2/Te/sub 3/-related materials.
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脉冲热压法制备Bi/sub - 2/Te/sub - 3/相关材料的热电性能
对Bi/sub 2/Te/sub 3/相关试样进行热压变形。采用Bridgman法对标称成分为Bi/sub 0.5/Sb/sub 1.5/Te/sub 3/和Bi/sub 2/Te/sub 2.85/Se/sub 0.15/ A的钢锭进行生长,并在脉冲电流加热下对钢锭进行热压变形。用x射线衍射分析了变形样品的晶体结构。所有的衍射峰都属于Bi/sub 2/Te/sub 3/型结构,图案表明样品在六边形(00/spl中点/l)平面上取向。霍尔效应测量表明,在80 ~ 300 K温度范围内,样品的载流子浓度为10/sup 25/ m/sup -3/数量级。变形后的功率因数大于源锭。结果表明,热压变形可以提高Bi/sub 2/Te/sub 3/相关材料的热电性能。
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