Hybrid PVK: OXD-7: QDs Emitting Layer for High Color Purified Quantum Dot Light Emitting-Diode

Hoang-Tuan Vu, Chih-Chiang Yang, Ba-Son Nguyen, Y. Su
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Abstract

In this paper, we proposed a novel hybrid quantum dot emitting layer (QD EML) for the efficient quantum dot light-emitting diodes (QLEDs). This proposed hybrid emitting layer consisted of a composite polymer with poly (9-vinlycarbazole) (PVK) and 1,3-bis[(4-tert-butylphenyl)-1,3,4oxadiazolyl]phenylene (OXD-7) in the weight ratio of 7:3 and high quantum yield CdSe@ZnS/ZnS quantum dots. By using PVK as hole transport and OXD-7 as electron transport polymer, both hole and electron was supported to inject into QD efficiently. Consequently, the maximum current efficiencies of 7.9 cd/A was achieved in QLEDs with the hybrid EML, which was $\sim 250$ % improvement over the bared EML-device. Moreover, high color purity and wavelength stable green QLEDs with peak wavelength of 536 nm was also obtained.
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混合PVK: OXD-7:高色纯量子点发光二极管的量子点发射层
本文提出了一种用于高效量子点发光二极管(qled)的新型混合量子点发光层(QD EML)。该杂化发光层由聚(9-乙烯咔唑)(PVK)和1,3-双[(4-叔丁基苯基)-1,3,4恶二唑]苯基(OXD-7)的复合聚合物组成,质量比为7:3,具有高量子产率CdSe@ZnS/ZnS量子点。利用PVK作为空穴输运,OXD-7作为电子输运聚合物,支持空穴和电子同时注入量子点。因此,使用混合EML的qled实现了7.9 cd/A的最大电流效率,比裸EML器件提高了250 %。此外,还获得了高色纯度和波长稳定的绿色qled,峰值波长为536 nm。
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