Magnetometry and NMR Study of Carbon Nanopowders Doped with Cobalt Nanoclusters and Self-assembly of their Polymer Nanocomposites under Magnetic Field

T. Gavasheli, Z. Shermadini, G. Ghvedashvili, Saba Suladze, G. Mamniashvili, T. Gegechkori, L. Rukhadze
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Abstract

The RF resonant magnetometry and NMR studies were carried out on carbon nanoparticles doped with magnetic cobalt clusters, which were synthesized by a technology combining of the hydrocarbon vapor pyrolysis and the chemical vapor deposition (CVD) process in a horizontal continuous reactor. The RF resonant magnetometry data show that the obtained carbon cobalt nanopowders are superparamagnetic at room temperatures and ferromagnetic at liquid nitrogen temperatures. The NMR study with the excitation by additional magnetic video-pulses of nanopowders obtained by using different hydrocarbons pyrolysis made it possible a fast assessment of their magnetic phase and hardness properties. The simple non-contact RF resonant magnetometry study of self-assembling processes in carbon cobalt polymer composite films synthesized using these nanopowders was made also.
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掺杂钴纳米团簇的碳纳米粉及其聚合物纳米复合材料在磁场下自组装的磁强学和核磁共振研究
采用碳氢蒸汽热解和化学气相沉积(CVD)相结合的工艺,在卧式连续反应器中合成了掺杂磁性钴团簇的纳米碳颗粒,并对其进行了射频共振磁强计和核磁共振研究。射频共振磁强计数据表明,制备的碳钴纳米粉体在室温下具有超顺磁性,在液氮温度下具有铁磁性。利用附加磁视频脉冲激励对不同碳氢化合物热解制备的纳米粉体进行核磁共振研究,可以快速评价其磁相和硬度特性。用简单的非接触射频共振磁强计研究了用这些纳米粉末制备的碳钴聚合物复合膜的自组装过程。
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