Simulation of Water Vapor Adsorption in a Fixed-bed Column with Silica Gel Material for Thermal Energy Storage Applications

Y. Carrier, C. Strong
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Abstract

Extended Abstract In order to reduce the environmental impact of fossil fuels and transition to a low-carbon economy, researchers around the world have been investing heavily in the development of renewable energy technologies. However, the renewable energy sources (e.g. wind power and solar energy) have the major constraint of intermittency and lack of consistency. Therefore, energy storage technologies play an important role in balancing the misalignment between the energy supply and demand, and creating a more flexible and reliable energy system [1]. Water vapor adsorption in porous materials in a fixed bed column can be used in the thermal energy storage (TES) systems for space heating applications. Various adsorbent materials have been tested and evaluated for their thermal energy storage abilities by our research group [2]-[6]. Silica gel has proven to be one of the better adsorbents with high energy storage density using low regeneration temperatures [5]. To gain a better understanding of this exothermic adsorption process, a mathematical model has been developed in this study, to simulate the water vapor adsorption process of silica gel material from humid air. The model included the mass and energy balances with equations to take into account the adsorption isotherms, the pressure-drop in the system, the heat of adsorption released during the process and the heat loss to the surroundings. The validated model can be used to optimize the TES system design and predict the TES system’s performance under operating conditions that we are not able to create in our laboratories.
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热储用硅胶材料固定床柱中水蒸气吸附的模拟
为了减少化石燃料对环境的影响,向低碳经济转型,世界各地的研究人员一直在大力投资可再生能源技术的开发。然而,可再生能源(如风能和太阳能)的主要制约因素是间歇性和缺乏一致性。因此,储能技术在平衡能源供需失衡,建立更加灵活可靠的能源系统方面发挥着重要作用[1]。多孔材料在固定床柱中的水蒸气吸附可用于空间加热应用的热能储存(TES)系统。我们课题组[2]-[6]对各种吸附剂材料的储热能力进行了测试和评估。硅胶已被证明是较好的吸附剂之一,在低再生温度下具有高能量储存密度[5]。为了更好地理解这种放热吸附过程,本研究建立了一个数学模型,模拟了硅胶材料从潮湿空气中吸附水蒸气的过程。该模型包括质量和能量平衡,以及考虑吸附等温线、系统压降、过程中释放的吸附热和向周围环境损失的方程。经过验证的模型可用于优化TES系统设计,并预测我们无法在实验室中创建的操作条件下TES系统的性能。
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