Rapid Fabrication of CNT Sensors Using Electro-chemical Deposition of Functionalized CNTs

W. Chow, M. Wong, W.J. Li, K. Wong
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引用次数: 3

Abstract

We present a novel fabrication technique to fabricate functionalized CNT sensors rapidly using electrochemical deposition method. The basic fabrication process of this sensor includes fabrication of a gold (Au) microelectrode array by photolithography process, functionalization of multi-walled carbon nanotubes (MWNTs) with carboxylic acid groups (-COOH), and electro-chemical deposition of functionalized MWNTs (f-CNTs) on the Au microelectrode array. The adhesion between the f-CNTs and the Au microelectrodes could be enhanced if CNT sensors are built using the process described in this paper. The I-V characteristics of the sensors were investigated. Our experimental results show that CNT sensors fabricated by electro-chemical process have dramatically different I-V characteristics compared with sensors fabricated by DEP or AFM manipulation techniques. The power limit of the sensors ranges from 0.28mW to 6.21mW, which is much higher than most reported CNT sensors. Self-heating effect can be induced at input power of ~2.2mW. Based on these experimental results, we think that the novel f-CNT sensors should be investigated further for applications in thermal, mechanical, and biomedical systems.
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电化学沉积功能化碳纳米管快速制备碳纳米管传感器
提出了一种利用电化学沉积法快速制备功能化碳纳米管传感器的新方法。该传感器的基本制造工艺包括通过光刻工艺制备金(Au)微电极阵列,用羧酸基(-COOH)将多壁碳纳米管(MWNTs)功能化,以及在金微电极阵列上电化学沉积功能化的MWNTs (f-CNTs)。如果采用本文描述的工艺构建碳纳米管传感器,则可以增强f-CNTs与Au微电极之间的粘附性。研究了传感器的I-V特性。实验结果表明,电化学工艺制备的碳纳米管传感器与DEP或AFM工艺制备的传感器具有显著不同的I-V特性。传感器的功率限制范围为0.28mW至6.21mW,远远高于大多数CNT传感器。当输入功率为~2.2mW时,可产生自热效应。基于这些实验结果,我们认为新型的f-CNT传感器应该进一步研究在热、机械和生物医学系统中的应用。
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