Investigation of Upgraded Technology for Plasma Spraying of Bronze Powder Using the Combined Process with Hydrocarbon Additions

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Abstract

The object of the research is thermal spray process for the formation of metal coating from bronze powder in plasma-fuel variant, using direct current (DC) electric arc plasma torch, on steel samples. The aim of the work was to investigate and develop the technology for plasma-fuel spraying of functional coatings (for wear-resistant and antimicrobial applications) on machine-building and medical purpose pieces with increased process capacity and moderate energy consumptions in a comparison with conventional thermal spray technologies with use of inert and oxygen-free gas media. During the study, using experimental and thermodynamic estimation methods, the thermal and chemical parameters of the process under the spraying conditions at ambient pressure were characterized, which made it possible to determine the area of preferred regimes of the developed technology. On the modernized testing unit for plasma spraying of metal powders with power of up to 40 kW, operating using a controlled combination of three types of gases – technical nitrogen and propane-butane (LPG) with compressed air, the measurement and optimization of the operating and constructive/assembling parameters of the system for aluminum bronze coating spraying were established. In this case, the experiments were carried out using the designed fuel intensifier, which is joined with the PP-25 arc plasma torch, as well as additional technological equipment (protective shroud). For samples of the resulting coatings with a thickness of 100 to 450 mm from the bronze material, testing of phase composition and some parameters of the resulting coatings on steel products was carried out. Operating capacity of the proposed process reaches 7–15 kg/h for bronze powder when using a moderate power of the torch – up to 35–40 kW and a limited flow rate of hydrocarbon gas (for example, LPG of the SPBT grade) – 0.1–0.35 kg/h. Analysis of the energy efficiency parameters of the developed technology, as well as its calculated technical characteristics, in a comparison with plasma and combined equipment of a similar purpose, showed that it has an advantage in terms of target indicators, in particular, in terms of energy consumption and total energy efficiency of the spraying unit, not less than 20–30 %. This makes it to proceed later to the stage of application of this technology into production based on a new process for the metal coating formation, in particular with antimicrobial properties, with improved energy efficiency of the process.
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添加烃复合工艺等离子喷涂青铜粉的改进工艺研究
研究了在等离子体燃料变体中,利用直流电弧等离子体炬在钢样品上热喷涂青铜粉末形成金属涂层的工艺。这项工作的目的是研究和开发在机械制造和医疗用途部件上使用等离子燃料喷涂功能涂层(用于耐磨和抗菌应用)的技术,与使用惰性和无氧气体介质的传统热喷涂技术相比,该技术具有更高的工艺能力和适度的能耗。在研究过程中,采用实验和热力学估计方法,表征了在环境压力下喷涂条件下的工艺热化学参数,从而确定了所开发技术的优选区域。在功率高达40 kW的金属粉末等离子喷涂现代化试验装置上,采用技术氮气和液化石油气(LPG)三种气体与压缩空气控制组合运行,建立了铝青铜涂层喷涂系统运行参数和构造/装配参数的测量和优化。在这种情况下,使用设计的燃料增强器进行实验,该增强器与PP-25电弧等离子炬以及附加的技术设备(保护罩)相连接。用青铜材料制备了厚度为100 ~ 450 mm的涂层样品,在钢制品上对涂层的相组成和一些参数进行了测试。当使用中等功率的火炬(高达35-40 kW)和有限流量的碳氢化合物气体(例如SPBT级的LPG) - 0.1-0.35 kg/h时,拟议工艺的铜粉操作能力达到7-15 kg/h。对所研制技术的能效参数进行了分析,并对其计算出的技术特点进行了分析,与同类目的的等离子及组合式设备进行了比较,结果表明,该技术在目标指标方面具有优势,特别是在喷涂装置的能耗和总能效方面不低于20 - 30%。这使得该技术进入了基于金属涂层形成的新工艺的生产应用阶段,特别是具有抗菌性能,并提高了该工艺的能源效率。
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