A simulation study of p-i-n amorphous silicon photovoltaic cell using ZnO nano rods

G. Ahmad, Sourav Mandal, T. K. Bhattacharya, J. Roy
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Abstract

Thinning down the active absorber layer is the current trend in solar cell technology. The thinner absorber layer has two main advantages (i) it reduces the material consumption and (ii) minimizes the time and energy required in production. For thin film silicon (Si) technology, thinning down the absorber layer is of particular interest since the device throughputs of vacuum deposition systems as well as the stability of the devices are significantly enhanced. The 3D nanorod structure in thin-film photovoltaics has got much attention due to their enhanced light trapping capability, and it also requires less thick active layer. The enhanced light trapping results in more efficient absorption of spectrum within the solar cell structure. This gives the higher short circuit current and hence higher power conversion efficiency. We have developed the ZnO nanorods on the glass substrate through galvanic cell based approach and designed a nanorod solar cell through numerical simulations using technology computer aided design (TCAD) tool. Numerical simulation shows that the highest conversion efficiency of 9.12% is obtained for the zinc oxide nanorod solar cell which is nearly 18.59% more than the planar a-Si:H solar cell with same absorber layer thickness.
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ZnO纳米棒对p-i-n非晶硅光伏电池的模拟研究
减薄有源吸收层是当前太阳能电池技术的发展趋势。较薄的吸收层有两个主要优点:(i)它减少了材料消耗和(ii)最大限度地减少了生产所需的时间和能量。对于薄膜硅(Si)技术,减薄吸收层是特别感兴趣的,因为真空沉积系统的器件吞吐量以及器件的稳定性都得到了显着增强。薄膜光伏中的三维纳米棒结构因其具有较强的光捕获能力和较薄的活性层而受到广泛关注。增强的光捕获导致太阳能电池结构内更有效地吸收光谱。这给了更高的短路电流,因此更高的功率转换效率。采用基于原电池的方法在玻璃基板上制备了ZnO纳米棒,并利用计算机辅助设计(TCAD)工具通过数值模拟设计了纳米棒太阳能电池。数值模拟结果表明,氧化锌纳米棒太阳能电池的最高转换效率为9.12%,比同等吸收层厚度的平面a-Si:H太阳能电池高出近18.59%。
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