Materials Technology

Abstract

The basic method of Ni reclamation from oxidized nickel (mostly laterite) ores is their pyrometallurgical processing. There are about 20 plants all over the World which process the ores and more then a half of them produces Ni in a form of ferronickel. The object of the development is recycling fine waste in a form of dust and sludge that is generated in large amounts at the majority of ferronickel enterprises. The current most common ferronickel technology includes several operations. They are pretreating of laterite ore by its crushing down to required small size particles and mixing it with lime and carbon reductant followed by calcining it in a rotary kiln. The produced calcine is smelted in submerged arc furnace for production of crude ferronickel with the unavoidable high carbon and silicon contents. The last melt stage is metal refining from these mostly undesirable elements by oxidation in converter. All stages and especially calcining operation are accompanied by fine waste generation. Calcining in rotary kiln is energy efficient operation. However it has very often insufficient utility in recycling agglomerates in a form of the pelletized or pressed waste without heat treating. The mechanical and the thermal stresses on the agglomerates occur during their motion through a tube of the kiln with a high temperature gradient. So the sufficient part of agglomerates is damaged. As a result the new portions of the fine waste are repeatedly generated at that time. Moreover the current tendency for broadening of usage of the tropical ores as ferronickel feedstock leads to sufficient increase of amount of the generated waste. The large wetness in the ores accompanied by their advanced brittleness accelerates formation of fines in rotary kilns. Currently the efforts for application of sintering process for agglomeration of the waste are being resumed in Ukraine. Sintering is the well known and the widely used method for ferrous metallurgy. However strength of the nickeliferous sinter produced by application of the traditional regimes and feedstock is sufficiently low. So it has been rarely applied in processing of the nickeliferous fines.