Dynamic mechanical properties of PP/MMT/OMMT nanocomposites

K. Hariprasad, M. Senthilkumar
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引用次数: 1

Abstract

This paper addresses the effect of nanoclays of two different nanoclays of montmorillonite (MMT) and organo-montmorillonite (OMMT) on morphology and dynamic mechanical properties of polypropylene (PP). The preparation of polymer nanocomposites by using a co-rotating twin screw extruder at filler loadings of 1, 3, 5 and 7 weight % using melt compounding PP with MMT and OMMT using polypropylene grafted maleic anhydride (PP-g-mA) as compatibilizer is described. First stage compositions with MMT content by different weight ratio PP/MMT nanocomposites were prepared and tested. Second stage compositions with OMMT content by different weight ratio PP/OMMT nanocomposites were prepared and tested. Third stage both combined MMT and OMMT equally mixed content by different weight ratio PP/MMT/OMMT nanocomposites were prepared and tested. Dynamic mechanical Analysis (DMA) indicated significant improvement in the storage modulus and loss modulus compared with neat PP.
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PP/MMT/OMMT纳米复合材料的动态力学性能
研究了蒙脱土(MMT)和有机蒙脱土(OMMT)两种不同的纳米粘土对聚丙烯(PP)形貌和动态力学性能的影响。介绍了以聚丙烯接枝马来酸酐(PP-g- ma)为相容剂,以熔融复合PP与MMT和OMMT为原料,在填充量为1、3、5和7 %的情况下,用同向旋转双螺杆挤出法制备聚合物纳米复合材料。制备了不同重量比的PP/MMT纳米复合材料,并对其进行了测试。采用不同重量比的PP/OMMT纳米复合材料制备了具有OMMT含量的第二阶段组合物并进行了测试。第三阶段制备了不同重量比的聚丙烯/MMT/OMMT纳米复合材料,并对其进行了测试。动态力学分析(DMA)表明,与纯PP相比,其存储模量和损耗模量有显著提高。
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