Carbon Dioxide – Based Energy Storage System: a Thermodynamic Approach

J. Lamotte, S. Poncet
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Abstract

Extended Abstract Compressed gas energy storage systems attract progressively the attention of researchers. Coupled to renewable energy sources, they enable to align the electrical energy demand with its production by overcoming their intermittency nature. They may also produce heating and cooling at the same time. They offer a green solution for remote communities but also for provinces where the price of electricity may highly vary during a day. The performances of systems working with air have been extensively evaluated thermodynamically and experimentally for decades and these technologies have already been implemented at a large scale (see the sites of Huntorf and MacIntosh). On the contrary, only few works focused on carbon dioxide as energy transfer medium. With the development of carbon dioxide capture and transport technologies, it appears as a nice way to massively revaluate CO2 and by the way to limit its emissions and climate change. After an exhaustive literature review on the capture, transport and utilization of carbon dioxide in energy storage systems, a thermodynamic model based on real fluid properties is developed. It evaluates the thermodynamic performances of an innovative cycle proposed recently by Liu et al. (2020). The influences of the turbine inlet pressure and temperature, compressor inlet and outlet pressures, charging/discharging times, the CO2 mass flowrate and isentropic efficiencies are quantified in details. Some improvements are then proposed to both diminish the price of the system and reduce the throttling losses by integrating transcritical ejectors. The integration of vortex tubes could be also beneficial for cooling and heating production.
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基于二氧化碳的储能系统:一种热力学方法
压缩气体储能系统日益受到研究人员的关注。与可再生能源相结合,它们能够克服其间歇性,使电能需求与其生产保持一致。它们也可能同时产生加热和冷却。它们不仅为偏远社区提供了绿色解决方案,也为一天内电价变化很大的省份提供了绿色解决方案。与空气一起工作的系统的性能已经被广泛地评估了几十年的热力学和实验,这些技术已经在大规模实施(见Huntorf和MacIntosh的网站)。相反,只有少数作品关注二氧化碳作为能量传递介质。随着二氧化碳捕获和运输技术的发展,这似乎是一种大规模重新评估二氧化碳的好方法,顺便限制其排放和气候变化。在对二氧化碳在储能系统中的捕获、传输和利用进行了详尽的文献综述之后,建立了一个基于真实流体性质的热力学模型。它评估了Liu等人(2020)最近提出的创新循环的热力学性能。详细量化了涡轮进口压力和温度、压气机进出口压力、充放电次数、CO2质量流量和等熵效率的影响。然后提出了一些改进措施,既降低了系统的价格,又通过集成跨临界喷射器减少了节流损失。涡流管的集成也可能有利于冷却和加热生产。
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