Renner Teller and Spin-orbit Perturbations in Triatomic Molecules

A. Alijah, G. Duxbury
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Abstract

Recent high resolution experimental studies of the electronic spectra of triatomic dihydrides and their ions have provided a severe test of current models of electronic orbital angular momentum-nuclear - vibrational angular momentum coupling. This coupling is associated with the breakdown of the Born-Oppenheimer separation of electronic orbital and nuclear motion, the Renner-Teller effect, and also with spin-orbit coupling.
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Renner Teller和三原子分子的自旋轨道微扰
最近对三原子二氢化物及其离子电子能谱的高分辨率实验研究,为当前的电子轨道角动量-核-振动角动量耦合模型提供了严格的检验。这种耦合与电子轨道和核运动的玻恩-奥本海默分离的破裂、雷纳-泰勒效应以及自旋-轨道耦合有关。
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