Metal Catalyzed Oxidation Reactions of Alkenes Using Eco-Friendly Oxidants

J. Soni, Pankaj Teli, Nusrat Sahiba, Ayushi Sethiya, S. Agarwal
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Abstract

Oxidation of alkenes is an important reaction in academia, industry and science as it is used to develop epoxides, carbonyls, allylic compounds, 1,2-diols, etc. Metal catalyzed oxidation of alkenes has aroused as a significant tool in modern organic synthesis. Several techniques are available; however some of them suffer from few shortcomings viz. high cost, toxic nature, harsh reaction condition, solid waste generation, etc. In view of these drawbacks, green oxidants i.e. O2, H2O2, TBHP, etc. have shown noteworthy prospects due to their nature, low cost, high atom economy and high sustainability in metal catalyzed reactions. This chapter highlights the metal catalyzed green oxidation of alkenes and shall provide new strategies for the functionalization and transformation of alkenes.
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环保氧化剂催化烯烃的金属氧化反应
烯烃的氧化反应是学术界、工业界和科学界的一个重要反应,因为它被用来生成环氧化合物、羰基、烯丙基化合物、1,2-二醇等。金属催化氧化烯烃已成为现代有机合成的重要手段。有几种技术可用;但有些方法存在成本高、毒性大、反应条件恶劣、产生固体废物等缺点。鉴于这些缺点,绿色氧化剂O2、H2O2、TBHP等因其性质好、成本低、原子经济性高、在金属催化反应中具有较高的可持续性而显示出值得关注的前景。本章重点介绍了金属催化烯烃的绿色氧化,为烯烃的功能化和转化提供了新的策略。
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