AMPEROMETRIC TITRATION WITH AIM OF DETERMINATION OF THE CORRELATION COEFFICIENTS

Abstract

Voltamperometric behavior of thioacetamide and its metallocomplexes on the platinum micro disk anode on different by nature and concentrations buffer solutions and phone electrolytes was investigated. Nature of limited anode currents and number of electron donation oxidation of one molecule of thioacetamide were determined and also the conditions of platinum(IV), palladium(II) and gold(III) determination by its solution were optimized. On the base of obtained data the possibility of using of elaborated electrochemical methods to analysis of some real objects and industrial materials was shown. With aim of elaboration of amperometric methods of platinum(IV), palladium(II) and gold(III) determination by thioacetamide solution and metrological value of obtained experimental data the coefficients of correlation were determined, the results of which are useful for analysis of different by nature standards samples, ores, mineral, tails and