Particle Transport via Three-Dimensional Chaotic Advection to Produce Electrically Conducting Plastics With Powder Additives

R. Danescu, D. Zumbrunnen
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Abstract

Extended micron-scale structures were produced in thermoplastic melts from initially large clusters of conducting carbon black particles transported by three-dimensional chaotic mixing. The structures formed networks that were captured by solidification and rendered the composite materials electrically conducting. A systematic study was carried out to assess the influence of key parameters and relate the electrical properties to the microstructures. Micrographs showed complex structures exhibiting patterns characteristic of chaos. Electrical measurements indicated that conductivity was achieved at carbon black concentrations significantly lower than achievable by common mixing methods, and lower than reported recently for two-dimensional chaotic mixing.
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粒子通过三维混沌平流输运制备粉末添加剂导电塑料
在热塑性熔体中,通过三维混沌混合传输的大型导电炭黑颗粒团簇产生了扩展的微米级结构。这些结构形成的网络被固化并使复合材料具有导电性。对关键参数的影响进行了系统的研究,并将电学性能与微观组织联系起来。显微照片显示出复杂的结构,表现出混沌的特征。电学测量表明,在炭黑浓度下获得的电导率明显低于普通混合方法,也低于最近报道的二维混沌混合。
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