Effect of the recipe on the properties of polymer-cement waterproofing mixtures

O. Kovalenko
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Abstract

The technological properties of polymer-cement mixtures and the physical and mechanical properties of polymer-cement waterproofing coatings, depending on their quantitative and qualitative composition: the ratio of cement:sand (C:S), water-cement ratio (W/C) and the content of modifying additives, have been investigated using the method of experimental-statistical modeling. As a result of the implementation of B3 plan and the processing of experimental data, experimental statistical models were obtained that express the effect of the recipy on the properties of polymer-cement waterproofing mixtures and coatings: mobility, compressive strength, bending strength, adhesion and impact strength and water absorption. It was found that having the constant values of C:S and W/C modifying additives, namely redispersing polymer powder, powder polycarboxylate superplasticizer and microsilica are an important factor in the formation of the structure and properties of waterproofing coatings. The analysis of the models showed that the redispersing polymer powder and superplasticizer have a positive effect on he mobility of polymer-cement waterproofing mixtures, while silica fume has a negative effect on this indicator. The effect of modifiers on the physical and mechanical properties of waterproofing coatings is following: redispersing polymer powder and superplasticizer have a negative effect on the compressive strength, while microsilica increases this indicator; redispersing polymer powder and microsilica increase the flexural strength, while the superplasticizer has a negative effect on this indicator; all investigated modifiers increase adhesion and impact strength and decrease water absorption. Based on experimental-statistical models, diagrams were constructed, which are a graphical representation of the effect of the recipe on the properties of polymer-cement waterproofing mixtures, which enables to determine the areas of the recipe use with specified properties.
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配方对聚合物-水泥防水混合料性能的影响
采用实验统计建模的方法,研究了聚合物-水泥混合料的工艺性能和聚合物-水泥防水涂料的物理力学性能,这取决于其定量和定性组成:水泥与砂的比(C:S)、水灰比(W/C)和改性添加剂的含量。通过B3方案的实施和实验数据的处理,得到了表达配方对聚合物-水泥防水混合料及涂料的流动性、抗压强度、抗弯强度、粘结强度和冲击强度、吸水率等性能影响的实验统计模型。研究发现,具有恒定的C:S和W/C改性添加剂,即再分散聚合物粉末、聚羧酸型粉末高效减水剂和微二氧化硅是形成防水涂料结构和性能的重要因素。模型分析表明,再分散聚合物粉和高效减水剂对聚合物-水泥防水混合料的流动性有正向影响,而硅灰对该指标有负向影响。改性剂对防水涂料物理力学性能的影响表现为:再分散聚合物粉和高效减水剂对防水涂料抗压强度有负面影响,而微二氧化硅提高了抗压强度;再分散聚合物粉和微二氧化硅提高了抗弯强度,而高效减水剂对抗弯强度有负面影响;所有研究的改性剂都能提高附着力和冲击强度,降低吸水率。在实验统计模型的基础上,构建了配方对聚合物-水泥防水混合料性能影响的图形表示图,从而确定具有特定性能的配方使用区域。
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