Preliminaries of the Decay of Metals versus Petroleum Oils

S. Aluvihara
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Abstract

Petroleum oils are predominantly made of various hydrocarbons with trace compounds including corrosive aided compounds that basically known as the salts, organic acids and various forms of sulfur. The scope of the current research was based on the investigations of the effect of salts, organic, elemental sulfur and Mercaptans of crude oils on the corrosion rates of seven different types of ferrous metals that important in the industry of crude oil refining. As the procedure the important corrosive properties of two different selected crude oils and the chemical compositions of the selected ferrous metals were analyzed by the standard instruments and methods. There were determined the corrosion rates of prepared metal coupons from selected ferrous metals with the similar dimensions after certain immersion time periods with respect to both crude oils by the weight loss method while analyzing the corroded metal surfaces through the microscope also simultaneously analyzed the decayed metallic elemental concentrations from metals into crude oils and the variations of initial hardness of the metals. As the foremost outcomes of the existing analysis there were obtained the significantly lower corrosion rates from stainless steels which are having at least 12% of chromium with sufficient amount if nickel, relatively higher corrosive impact from salts especially at the lower temperatures, formations of ferrous sulfides, ferrous oxides, corrosion cracks and pitting corrosion, significantly decay of copper from Monel metal, higher decay of ferrous from some of carbon steels and slight reductions of the initial hardness of metals after the formations of the corrosion on the metal surfaces.
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金属对石油的衰变初探
石油主要是由各种碳氢化合物和微量化合物组成的,包括腐蚀性化合物,这些化合物基本上被称为盐、有机酸和各种形式的硫。目前的研究范围是基于对原油中盐、有机物、单质硫和硫醇对原油炼制工业中重要的七种不同类型黑色金属腐蚀速率的影响的研究。在此过程中,用标准仪器和方法分析了两种不同的原油的重要腐蚀性能和所选黑色金属的化学成分。选取尺寸相近的黑色金属,用失重法测定了两种原油浸泡一定时间后制备的金属薄片的腐蚀速率,同时用显微镜对腐蚀后的金属表面进行了分析,同时分析了金属在原油中的衰变金属元素浓度和金属初始硬度的变化。现有分析的主要结果是,铬含量至少为12%且镍含量足够的不锈钢的腐蚀速率明显较低,盐的腐蚀影响相对较高,特别是在较低温度下,硫化铁、氧化亚铁的形成,腐蚀裂纹和点蚀,铜从蒙乃尔金属中明显衰变,在金属表面形成腐蚀后,某些碳钢的腐蚀率较高,金属的初始硬度略有降低。
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