A FLUORESCENCE CONTRIBUTION TO THE RECOGNITION OF FLUIDS TRAPPED IN MINERALS IN THE CARPATHIAN OUTCROPS

K. Jarmołowicz-Szulc
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Abstract

Based on the assumption that fluorescence studies are an important tool in search and characterization of hydrocarbons, samples of rocks, minerals and the organic matter were collected in the Western Carpathian area spreading from the Mszana Górna region in the west to the Bieszczady Mts. in the east, and continuously, towards SE outside the Polish frontier, in Ukraine and Slovakia. Analytical procedures comprised preparation, microscopic observation of the material (organic matter and minerals) from the point of view of inclusions and fluorescence followed by detailed luminescence studies. Those steps have been followed by the microthermometric determinations. The application of the fluid inclusion methods, which are one of the newest analytical tools in the last two decades have led to the characteristics of fluids trapped in the inclusions in the area. The fluorescence studies showed some diversity of hydrocarbons both in compositions and in distribution. The analyses were performed in double-sided polished thin sections prepared based on cold techniques. Fluorescence of inclusions in two minerals, quartz and calcite, was checked in those specific thin sections either in glued wafers, or loose (single) crystals. The fluid inclusion studies were accompanied later on by solid organic matter inclusion studies. Those point to the presence of the following minerals: quartz, dolomite, calcite, clay minerals, gypsum with anhydrite admixture, traces of pyrite and siderite, feldspars. General distribution of fluorescing and not fluorescing inclusions suggests the presence of light hydrocarbons (methane) in the west and south of the area, being enriched in higher hydrocarbons (oil) towards the east.
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荧光有助于识别喀尔巴阡山脉露头矿物中捕获的流体
基于荧光研究是寻找和表征碳氢化合物的重要工具的假设,从西部的Mszana Górna地区到东部的Bieszczady mss地区,在西喀尔巴阡山脉地区收集了岩石、矿物和有机质样品,并不断向波兰边境以外的东南方向,在乌克兰和斯洛伐克。分析程序包括制备,从包裹体和荧光的角度对材料(有机物和矿物质)进行微观观察,然后进行详细的发光研究。在这些步骤之后进行了显微测温。流体包裹体方法是近二十年来最新的分析工具之一,该方法的应用使该地区包裹体中流体的特征得以揭示。荧光研究表明,其碳氢化合物在组成和分布上都有一定的多样性。分析是在基于冷技术制备的双面抛光薄片上进行的。两种矿物(石英和方解石)的内含物的荧光,在胶合晶圆或松散(单晶)的特定薄片中进行了检查。流体包裹体的研究随后伴随着固体有机质包裹体的研究。这些指出了以下矿物的存在:石英,白云石,方解石,粘土矿物,石膏与硬石膏混合物,黄铁矿和菱铁矿的痕迹,长石。荧光包裹体和非荧光包裹体的总体分布表明,该区西部和南部存在轻烃(甲烷),东部富集高级烃(油)。
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