Synthesis and optical properties of shaped gold nanomaterials under dark-field microscope

Cheng-An J Lin, Yi-Ting Lin, Zih-Yun Huang, Zhi-Wei Chen, Yu-Cheng Chou, Walter H. Chang
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Abstract

Nanophotonics has raised a great attention because detection limit can easily go down to the molecular level. Herein, we present a dark-field integrated Light-eye Technology (iLeyeT) system for monitoring of polarization-dependent surface plasmons of single shaped nanomaterials. Single shaped gold nanomaterial such as gold nanorod present both longitudinal and transverse surface plasmonic resonance under dark-field microscope. The orientation of single nanomaterials significantly tunes the direction of polarized light. We introduce a programmable light source into the dark-field microscope and image the relative peak intensities of the transverse and longitudinal surface plasmon via fast tuning wavelength. The signals from single nanomaterials can be visualized and detected by the dark-field iLeyeT system.
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暗场显微镜下异形金纳米材料的合成及其光学性质
纳米光子学由于其检测极限可以很容易地降低到分子水平而引起了人们的广泛关注。在此,我们提出了一个暗场集成光眼技术(iLeyeT)系统,用于监测单形纳米材料的极化依赖表面等离子体。在暗场显微镜下,金纳米棒等单晶金纳米材料同时表现出纵向和横向表面等离子体共振。单个纳米材料的取向显著地改变了偏振光的方向。我们在暗场显微镜中引入可编程光源,并通过快速调谐波长成像横向和纵向表面等离子体的相对峰值强度。利用暗场iLeyeT系统可以对单个纳米材料的信号进行可视化和检测。
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