Preparation of Titanium Oxide-Fibrous Zeolite Y Catalyst for Desulfurization of Fuel

A. Mutalib, N. F. Jaafar, T. Torlaema, N. Salamun
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Abstract

In this study, TiO2 supported on fibrous Zeolite Y (FY) was synthesized via ultrasonic co-impregnation for desulfurization of dibenzothiophene (DBT). The physicochemical properties of the prepared TiO2/FY were characerized by XRD and TEM. Next, to determine the efficiency capacity of TiO2/FY in the fuel desulfurization process, several photocatalytic tests with different parameters including time (0 – 180 min), TiO2/FY dosage (0.1 - 5 g/L), initial pH (2 - 8), and initial concentration (50 – 400 mg/L) were conducted accordingly. A high DBT removal (87%) was successfully accomplished at the optimum conditions of 5 g/L TiO2/FY, pH 8, and 300 mg/L, which may be contributed from the fibrous structure as recorded by TEM and high crystallinity from the XRD analysis. It can be concluded that the TiO2/FY own great potential to be applied as an efficient material for the fuel desulphurization.
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燃料脱硫用氧化钛-纤维型沸石Y催化剂的制备
本研究采用超声共浸渍法制备了负载在Y型分子筛(FY)上的TiO2,用于二苯并噻吩(DBT)的脱硫。采用XRD和TEM对制备的TiO2/FY的理化性质进行了表征。接下来,为了确定TiO2/FY在燃料脱硫过程中的效率容量,进行了不同时间(0 ~ 180 min)、TiO2/FY用量(0.1 ~ 5 g/L)、初始pH(2 ~ 8)、初始浓度(50 ~ 400 mg/L)的光催化试验。在TiO2/FY为5 g/L、pH为8、pH为300 mg/L的条件下,样品的DBT去除率达到了87%,这可能与透射电镜观察到的纤维结构和XRD分析得出的高结晶度有关。由此可见,TiO2/FY作为一种高效的燃料脱硫材料具有很大的应用潜力。
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