Study on spectral lines to improve the measurement accuracy of H2O molecular concentration based on TDLAS technology

Yifan Wang, Jinfeng Zhou, Yung-chul Ju, Xiaosong Shi, Yuhan Zhang, Shaojie Guan
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Abstract

H2O is an important molecule in the atmosphere, which is closely related to climate change and industrial applications (such as combustion process). The detection of trace water vapor concentration is of great significance in earth ecology and industrial production. Tunable diode laser absorption spectroscopy (TDLAS) inverses the gas concentration by measuring the gas absorption spectrum. The wavelength of the common characteristic absorption peak of H2O molecule is 7181.16 cm-1. The spectral absorption peaks of different wavelengths are analyzed in the paper. It is proved that when 7306.75 cm-1 characteristic absorption peak is used to replace 7181.16 cm-1 characteristic absorption peak for concentration inversion, the influence can be reduced and the measurement accuracy can be improved by combining the target peak with the interference peak.
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基于TDLAS技术提高水分子浓度测量精度的谱线研究
H2O是大气中的重要分子,与气候变化和工业应用(如燃烧过程)密切相关。微量水蒸气浓度的检测在地球生态和工业生产中具有重要意义。可调谐二极管激光吸收光谱(TDLAS)通过测量气体吸收光谱来反演气体浓度。H2O分子的共同特征吸收峰波长为7181.16 cm-1。对不同波长的光谱吸收峰进行了分析。实验证明,用7306.75 cm-1特征吸收峰代替7181.16 cm-1特征吸收峰进行浓度反演时,将目标峰与干扰峰结合,可以减小影响,提高测量精度。
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