{"title":"Corrosion studies of DC reactive magnetron sputtered alumina coating on 304 SS","authors":"Baskar Thangaraj, K. Mahadevan","doi":"10.1515/eetech-2017-0001","DOIUrl":null,"url":null,"abstract":"Abstract Aluminum oxide films on SS 304 deposited by DC reactive magnetron sputtering technique were studied with respect to the composition of the sputter gas (Ar:O2), gas pressure, substrate temperature, current etc. to achieve good insulating films with high corrosion resistance. The films were characterized by XRD and SEM techniques. Potentiodynamic polarization and electrochemical impedance spectroscopy measurements were made under static conditions in order to evaluate the corrosion performance of the alumina-coated SS 304 for various immersion durations in 0.5 M and 1 M NaCl solution. Alumina-coated SS 304 has low corrosion value of 0.4550 and 1.1090MPY for 24 h immersion time in both solutions. The impedance plots for the alumina coated SS 304 in 1 M NaCl solution at different durations are slightly different to when compared to its immersion in 0.5 M NaCl solutions and are composed of two depressed semi circles. For the alumina coated film, the impedance spectrum decreased, when immersion time increased.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"7 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2017-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochemical Energy Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/eetech-2017-0001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
Abstract Aluminum oxide films on SS 304 deposited by DC reactive magnetron sputtering technique were studied with respect to the composition of the sputter gas (Ar:O2), gas pressure, substrate temperature, current etc. to achieve good insulating films with high corrosion resistance. The films were characterized by XRD and SEM techniques. Potentiodynamic polarization and electrochemical impedance spectroscopy measurements were made under static conditions in order to evaluate the corrosion performance of the alumina-coated SS 304 for various immersion durations in 0.5 M and 1 M NaCl solution. Alumina-coated SS 304 has low corrosion value of 0.4550 and 1.1090MPY for 24 h immersion time in both solutions. The impedance plots for the alumina coated SS 304 in 1 M NaCl solution at different durations are slightly different to when compared to its immersion in 0.5 M NaCl solutions and are composed of two depressed semi circles. For the alumina coated film, the impedance spectrum decreased, when immersion time increased.
摘要:采用直流反应磁控溅射技术,对溅射气体(Ar:O2)的组成、气体压力、衬底温度、电流等因素进行了研究,得到了具有良好绝缘性能和高耐蚀性的s304表面氧化铝膜。采用XRD和SEM对膜进行了表征。在静态条件下,通过动电位极化和电化学阻抗谱测量,评价了氧化铝涂层SS 304在0.5 M和1 M NaCl溶液中不同浸泡时间的腐蚀性能。镀铝SS 304在两种溶液中浸泡24 h时,腐蚀值较低,分别为0.4550和1.1090MPY。氧化铝包覆的SS 304在1 M NaCl溶液中不同时间的阻抗图与浸泡在0.5 M NaCl溶液中的阻抗图略有不同,由两个凹陷的半圆组成。氧化铝涂层的阻抗谱随浸泡时间的增加而减小。