Pub Date : 2021-01-01DOI: 10.1515/eetech-2020-0100
Yuping Wu, R. Holze
Abstract Self-discharge as an omnipresent and unwelcome feature of electrochemical storage devices driven by fundamental forces is briefly introduced and put into perspective. Causes and observed effects as well as possible consequences and modifications in support of a therapy of these effects are described. Care is taken to consider observed phenomena with respect to different types of supercapacitors and different classes of electrode materials and additives inside a cell. Modeling and further theoretical approaches are presented. Recommendations for reporting and data presentation are provided.
{"title":"Self-discharge in supercapacitors: Causes, effects and therapies: An overview","authors":"Yuping Wu, R. Holze","doi":"10.1515/eetech-2020-0100","DOIUrl":"https://doi.org/10.1515/eetech-2020-0100","url":null,"abstract":"Abstract Self-discharge as an omnipresent and unwelcome feature of electrochemical storage devices driven by fundamental forces is briefly introduced and put into perspective. Causes and observed effects as well as possible consequences and modifications in support of a therapy of these effects are described. Care is taken to consider observed phenomena with respect to different types of supercapacitors and different classes of electrode materials and additives inside a cell. Modeling and further theoretical approaches are presented. Recommendations for reporting and data presentation are provided.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"81 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131629616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.1515/eetech-2020-0101
Jessica Roscher, Dan Liu, R. Holze
Abstract The suitability of three electrochemical methods commonly used for the assessment of efficiency of corrosion inhibitors in practical applications has been examined by a direct comparison of relevant results with an aromatic corrosion inhibitor as example. Discrepancies between results are discussed, practical approaches taking inherent weaknesses of the methods are indicated.
{"title":"Concentration-dependent corrosion inhibition with electrochemical energy conversion systems by a disubstituted aromatic: A comparison of methods","authors":"Jessica Roscher, Dan Liu, R. Holze","doi":"10.1515/eetech-2020-0101","DOIUrl":"https://doi.org/10.1515/eetech-2020-0101","url":null,"abstract":"Abstract The suitability of three electrochemical methods commonly used for the assessment of efficiency of corrosion inhibitors in practical applications has been examined by a direct comparison of relevant results with an aromatic corrosion inhibitor as example. Discrepancies between results are discussed, practical approaches taking inherent weaknesses of the methods are indicated.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134226050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-01-01DOI: 10.1515/eetech-2019-0001
Yu Ge, Md. Ikram Ul Hoque, Q. Qu
Abstract 1D α-hematite nanorods synthesized by a simple, scalable and novel green chemistry method exhibit fast kinetics of the interfacial Faradaic redox reaction yielding a specific capacitance of 140 F·g−1 when used as a battery-type electrode in a supercapacitor. Ample supply and environmental compatibility of the raw material suggest the use of this material. Insufficient stability suggest further investigations.
{"title":"1D Hematite-[α-Fe2O3]-nanorods prepared by green fabrication for supercapacitor electrodes","authors":"Yu Ge, Md. Ikram Ul Hoque, Q. Qu","doi":"10.1515/eetech-2019-0001","DOIUrl":"https://doi.org/10.1515/eetech-2019-0001","url":null,"abstract":"Abstract 1D α-hematite nanorods synthesized by a simple, scalable and novel green chemistry method exhibit fast kinetics of the interfacial Faradaic redox reaction yielding a specific capacitance of 140 F·g−1 when used as a battery-type electrode in a supercapacitor. Ample supply and environmental compatibility of the raw material suggest the use of this material. Insufficient stability suggest further investigations.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"50 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122334473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-12-01DOI: 10.1515/eetech-2018-0007
M. Venkateswarlu, T. Balusamy, K. Murthy, M. Jagadish, S. Vijayanand
Abstract The lead acid battery technology has undergone several modifications in the recent past, in particular, the electrode grid composition, oxide paste recipe with incorporation of foreign additives into the electrodes and similarly additives added in the electrolytes to improve electrical performance of the lead acid battery. In this paper, the electrochemical behavior of the lead electrodes with different weight/volume percentages (wt./v%) of MgSO4(0.0., 0.5., 1.0., 2.0., and 5.0) added into the electrolyte have been investigated with cyclic voltammetry (CV), linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The CV profile showed better redox behavior of the lead electrodes which was attributed to the increased active surface area of the electrode. Further studies of the gas evolution found a mixed trend and a considerable drop in the impedance as observed by LSV and EIS analysis as compared to the blank electrolyte solution. The influence of a modified electrolyte on the electrochemical activity of the lead electrodes is correlated and discussed.
{"title":"Effect of magnesium sulfate on the electrochemical behavior of lead electrodes for lead acid batteries","authors":"M. Venkateswarlu, T. Balusamy, K. Murthy, M. Jagadish, S. Vijayanand","doi":"10.1515/eetech-2018-0007","DOIUrl":"https://doi.org/10.1515/eetech-2018-0007","url":null,"abstract":"Abstract The lead acid battery technology has undergone several modifications in the recent past, in particular, the electrode grid composition, oxide paste recipe with incorporation of foreign additives into the electrodes and similarly additives added in the electrolytes to improve electrical performance of the lead acid battery. In this paper, the electrochemical behavior of the lead electrodes with different weight/volume percentages (wt./v%) of MgSO4(0.0., 0.5., 1.0., 2.0., and 5.0) added into the electrolyte have been investigated with cyclic voltammetry (CV), linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The CV profile showed better redox behavior of the lead electrodes which was attributed to the increased active surface area of the electrode. Further studies of the gas evolution found a mixed trend and a considerable drop in the impedance as observed by LSV and EIS analysis as compared to the blank electrolyte solution. The influence of a modified electrolyte on the electrochemical activity of the lead electrodes is correlated and discussed.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"4 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129680587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Graphite felt (GF) with numerous merits has been widely used as electrode in all-vanadium redox flow batteries (VRFB), but its further application is still hindered by its intrinsically poor electrocatalytic activity. Herein, we propose a three-dimensional (3D) conducting network constructed with reduced graphene oxide (rGO) in the GF electrode via a two-step method. The 3D conducting network with abundant oxygen-containing functional groups in the GF is conducive to the transport of electrons between GF fibers and the electrochemical charge transfer to vanadium ions in the composite electrode; it can enhance the electrocatalytic activity and conductivity of GF. The VRFB using 3D rGO modified GF (mGF) electrode exhibited outstanding energy efficiency of 73.4% at a current density of 100 mA·cm−2, which is much higher than that with pristine GF (pGF) (65.4%); and better rate capability. These first results reveal that GF with 3D conducting network shows promising opportunities for the VRFB and other electrochemical flow systems
{"title":"A three-dimensional conducting network of rGO-in-graphite-felt as electrode for vanadium redox flow batteries","authors":"Hongrui Wang, Wei Ling, Jizhong Chen, Zhian Wang, Xian‐Xiang Zeng, Yongqing Hu, Xiongwei Wu, Qi Deng, Guanghui Chen, Yuping Wu, R. Holze","doi":"10.1515/eetech-2018-0008","DOIUrl":"https://doi.org/10.1515/eetech-2018-0008","url":null,"abstract":"Abstract Graphite felt (GF) with numerous merits has been widely used as electrode in all-vanadium redox flow batteries (VRFB), but its further application is still hindered by its intrinsically poor electrocatalytic activity. Herein, we propose a three-dimensional (3D) conducting network constructed with reduced graphene oxide (rGO) in the GF electrode via a two-step method. The 3D conducting network with abundant oxygen-containing functional groups in the GF is conducive to the transport of electrons between GF fibers and the electrochemical charge transfer to vanadium ions in the composite electrode; it can enhance the electrocatalytic activity and conductivity of GF. The VRFB using 3D rGO modified GF (mGF) electrode exhibited outstanding energy efficiency of 73.4% at a current density of 100 mA·cm−2, which is much higher than that with pristine GF (pGF) (65.4%); and better rate capability. These first results reveal that GF with 3D conducting network shows promising opportunities for the VRFB and other electrochemical flow systems","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"212 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132334846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-07-11DOI: 10.1515/eetech-2018-0006
N. S. Bagal, V. S. Kathavate, P. Deshpande
Abstract The present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).
{"title":"Nano-TiO2 Phosphate Conversion Coatings – A Chemical Approach","authors":"N. S. Bagal, V. S. Kathavate, P. Deshpande","doi":"10.1515/eetech-2018-0006","DOIUrl":"https://doi.org/10.1515/eetech-2018-0006","url":null,"abstract":"Abstract The present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121235416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE), a kind of fluorinated ether, was used as an electrolyte additive for Li-S batteries. A compact, smooth, and homogenous surface layer was formed on lithium anode at the optimized amount of added TTE. In addition, TTE additive played a crucial role in modifying the composition of the passivation layer on the sulfur/carbon cathode. Consequently, the dissolution and shuttling of polysulfides were effectively prevented. The reversible capacity, initial coulombic efficiency, electrode reaction kinetic, and cycling stability of Li-S batteries were greatly improved.
{"title":"Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries","authors":"Feng Qian, Jie Shao, Yu Chen, Guobin Zhu, Q. Qu, Honghe Zheng","doi":"10.1515/eetech-2018-0005","DOIUrl":"https://doi.org/10.1515/eetech-2018-0005","url":null,"abstract":"Abstract 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE), a kind of fluorinated ether, was used as an electrolyte additive for Li-S batteries. A compact, smooth, and homogenous surface layer was formed on lithium anode at the optimized amount of added TTE. In addition, TTE additive played a crucial role in modifying the composition of the passivation layer on the sulfur/carbon cathode. Consequently, the dissolution and shuttling of polysulfides were effectively prevented. The reversible capacity, initial coulombic efficiency, electrode reaction kinetic, and cycling stability of Li-S batteries were greatly improved.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"16 1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116790862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-15DOI: 10.1515/eetech-2018-0004
V. S. Channu, B. Rambabu, K. Kumari, Rajmohan R. Kalluru, R. Holze
Abstract Tin oxide (SnO2) nanostructures and SnO2/Polyaniline (PANI) nanocomposites to be used as electrode materials for a lithium ion battery were synthesized using a solution-route technique with chelating agents followed by calcination at 300∘C for 4 h. Structural and morphological properties were studied with powder X-ray diffraction, scanning electron and transmission electron microscopy. Particles of 25-10 nm size are observed in the microscope images. TGA results showed that the PANI-modified SnO2 nanoparticles exhibit higher thermal stability than the SnO2 nanoparticles. Electrochemical properties of SnO2 and SnO2/PANI electrodes were examined in a lithium ion battery and a supercapacitor. The electrode of SnO2/PANI shows higher specific capacity. The cell with SnO2/PANI exhibits a specific capacity of 1450 mAh/g at C/10. Supercapacitor results indicate that the PANI-modified SnO2 composite had a higher current with apparent cathodic and anodic peaks.
{"title":"SnO2/PANI nanocomposite electrodes for supercapacitors and lithium ion batteries","authors":"V. S. Channu, B. Rambabu, K. Kumari, Rajmohan R. Kalluru, R. Holze","doi":"10.1515/eetech-2018-0004","DOIUrl":"https://doi.org/10.1515/eetech-2018-0004","url":null,"abstract":"Abstract Tin oxide (SnO2) nanostructures and SnO2/Polyaniline (PANI) nanocomposites to be used as electrode materials for a lithium ion battery were synthesized using a solution-route technique with chelating agents followed by calcination at 300∘C for 4 h. Structural and morphological properties were studied with powder X-ray diffraction, scanning electron and transmission electron microscopy. Particles of 25-10 nm size are observed in the microscope images. TGA results showed that the PANI-modified SnO2 nanoparticles exhibit higher thermal stability than the SnO2 nanoparticles. Electrochemical properties of SnO2 and SnO2/PANI electrodes were examined in a lithium ion battery and a supercapacitor. The electrode of SnO2/PANI shows higher specific capacity. The cell with SnO2/PANI exhibits a specific capacity of 1450 mAh/g at C/10. Supercapacitor results indicate that the PANI-modified SnO2 composite had a higher current with apparent cathodic and anodic peaks.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123679305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-05-30DOI: 10.1515/eetech-2018-0003
K. Ramanujam, T. Thirupathi
Abstract This study reports a synthesis of carbon supported graphitic carbon nitride (g-C3N4-KBC) obtained by pyrolysis of melamine with Ketjenblack 600JD carbon (KBC) at 550°C for 4 h in a N2 atmosphere. g-C3N4-KBC oxidizes hydrazine at an onset potential 0.145 V vs. SCE close to the thermodynamic standard potential of hydrazine (0.23 V vs. SHE). In comparison to the controls, KBC and g-C3N4, g-C3N4-KBC oxidizes hydrazine at lower overpotential.Most research has tended to focus on transition metal-based catalysts and few are of carbon material such as graphene nanoflakes, graphene oxide, and carbon nanotubes. A comparison in terms of sensitivity, detection range and stability reveals g-C3N4-KBC electrode’s superiority over other carbon material-based catalysts. To the best of our knowledge, the g-C3N4-KBC catalyst is not reported for sensing hydrazine in the literature.
{"title":"Carbon supported g-C3N4 for electrochemical sensing of hydrazine","authors":"K. Ramanujam, T. Thirupathi","doi":"10.1515/eetech-2018-0003","DOIUrl":"https://doi.org/10.1515/eetech-2018-0003","url":null,"abstract":"Abstract This study reports a synthesis of carbon supported graphitic carbon nitride (g-C3N4-KBC) obtained by pyrolysis of melamine with Ketjenblack 600JD carbon (KBC) at 550°C for 4 h in a N2 atmosphere. g-C3N4-KBC oxidizes hydrazine at an onset potential 0.145 V vs. SCE close to the thermodynamic standard potential of hydrazine (0.23 V vs. SHE). In comparison to the controls, KBC and g-C3N4, g-C3N4-KBC oxidizes hydrazine at lower overpotential.Most research has tended to focus on transition metal-based catalysts and few are of carbon material such as graphene nanoflakes, graphene oxide, and carbon nanotubes. A comparison in terms of sensitivity, detection range and stability reveals g-C3N4-KBC electrode’s superiority over other carbon material-based catalysts. To the best of our knowledge, the g-C3N4-KBC catalyst is not reported for sensing hydrazine in the literature.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128627633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-04-28DOI: 10.1515/eetech-2018-0002
V. Divya, M. Sangaranarayanan
Abstract Nanostructured conducting polymers have received immense attention during the past few decades on account of their phenomenal usefulness in diverse contexts, while the interface between two immiscible liquids is of great interest in chemical and biological applications. Here we propose a novel Electrode(solid)/Electrolyte(aqueous)/Electrolyte(organic) Interfacial assembly for the synthesis of polymeric nanostructures using a novel concept of three diffuse double layers. There exist remarkable differences between the morphologies of the polymers synthesized using the conventional electrode/electrolyte method and that of the new approach. In contrast to the commonly employed electrodeposition at liquid/liquid interfaces, these polymer modified electrodes can be directly employed in diverse applications such as sensors, supercapacitors etc.
{"title":"Electrodeposition of Polymer Nanostructures using Three Diffuse Double Layers: Polymerization beyond the Liquid/Liquid Interfaces","authors":"V. Divya, M. Sangaranarayanan","doi":"10.1515/eetech-2018-0002","DOIUrl":"https://doi.org/10.1515/eetech-2018-0002","url":null,"abstract":"Abstract Nanostructured conducting polymers have received immense attention during the past few decades on account of their phenomenal usefulness in diverse contexts, while the interface between two immiscible liquids is of great interest in chemical and biological applications. Here we propose a novel Electrode(solid)/Electrolyte(aqueous)/Electrolyte(organic) Interfacial assembly for the synthesis of polymeric nanostructures using a novel concept of three diffuse double layers. There exist remarkable differences between the morphologies of the polymers synthesized using the conventional electrode/electrolyte method and that of the new approach. In contrast to the commonly employed electrodeposition at liquid/liquid interfaces, these polymer modified electrodes can be directly employed in diverse applications such as sensors, supercapacitors etc.","PeriodicalId":443383,"journal":{"name":"Electrochemical Energy Technology","volume":"177 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134136770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}