Enhancement in Electrical Conductivity of Transparent Single-Walled Carbon Nanotube Films

Byung-Seon Kong, Hee‐Tae Jung, Sounghee Park, Moon-ki Park
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Abstract

We have developed a simple and practical method to enhance the electrical conductivity of single-walled carbon nanotube (SWNT) films without loss of their transparency. In order to achieve an enhanced conductivity of transparent SWNT films, we carried out the formation of gold nanoparticles through the reduction of gold ions (Au3+) onto the SWNT films which manufactured by the vacuum filtration method. The electroless reduction of gold ions results from redox reactions between Au3+ and SWNT sidewalls just by immersion bare SWNT films into an ethanolic aqueous solution of gold salt (HAuCl4) for several minutes. After the formation of gold nanoparticles, the electrical conductivity increased over two-fold of the initial conductivity and maintained the visible light transmittance ~80 %.
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透明单壁碳纳米管薄膜电导率的增强
我们开发了一种简单实用的方法来提高单壁碳纳米管(SWNT)薄膜的导电性而不损失其透明度。为了提高透明SWNT薄膜的导电性,我们将金离子(Au3+)还原到真空过滤法制备的SWNT薄膜上,形成了金纳米颗粒。金离子的化学还原是由Au3+与SWNT侧壁之间的氧化还原反应引起的,只需将裸露的SWNT膜浸入金盐(HAuCl4)的乙醇水溶液中几分钟。金纳米颗粒形成后,电导率比初始电导率提高2倍以上,可见光透过率维持在80%左右。
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