The effect of TiB/sub 2/ addition on the thermoelectric properties of B/sub 4/C ceramics

K. Cai, C. Nan
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Abstract

B/sub 4/C-TiB/sub 2/ composites were prepared via hot-pressing. The thermal conductivity, electrical conductivity and Seebeck coefficient of samples containing 0, 12, 16, 20 vol% TiB/sub 2/ are measured from room temperature up to 1200 K. The results show that the electrical conductivity and thermal conductivity increase with TiB/sub 2/ content and that the Seebeck coefficient decreases with TiB/sub 2/ content. The value of dimensionless figure of merit of 12% TiB/sub 2/ sample is always higher than that of 0% TiB/sub 2/ sample in the whole temperature range, and that of 16% TiB/sub 2/ samples is also higher than that of 0% TiB/sub 2/ sample as T<700 K and similar as T>700K, while that of 20% TiB/sub 2/ samples is lower than that of 0% TiB/sub 2/ sample due to its higher thermal conductivities and lower Seebeck coefficients than those of 0% TiB/sub 2/ sample. These results indicate that it is possible to improve the thermoelectric properties of pure materials by selecting an optimum combination of different materials.
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TiB/ sub2 /添加量对B/ sub4 /C陶瓷热电性能的影响
采用热压法制备了B/sub - 4/C-TiB/sub - 2/复合材料。在室温至1200 K范围内测量了含0、12、16、20 vol% TiB/sub 2/样品的导热系数、电导率和塞贝克系数。结果表明:随着TiB/sub 2/含量的增加,材料的电导率和导热系数增大,Seebeck系数减小;在整个温度范围内,12% TiB/sub - 2/试样的无因次优值始终高于0% TiB/sub - 2/试样,16% TiB/sub - 2/试样的无因次优值也高于0% TiB/sub - 2/试样的T700K,而20% TiB/sub - 2/试样的无因次优值低于0% TiB/sub - 2/试样,这是由于其导热系数高于0% TiB/sub - 2/试样,塞贝克系数低于0% TiB/sub - 2/试样。这些结果表明,通过选择不同材料的最佳组合,可以改善纯材料的热电性能。
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