Marine fuel with low sulfur content, production prospects in Ukraine.

Сhernyavsky А.V., Grigorov A.B.
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Abstract

The article considers the main global trends in the use of fuel for shipping. The necessity of replacing marine fuel oils of the F-5 and F-12 grades, which are currently widely used by the merchant fleet of Ukraine, with new fuels with a low sulfur content, such as marine gas oil (MGO) or low sulfur marine gas oil (LS-MGO), is substantiated. The main problems are characterized, and in turn, they may arise during the transition of shipping to new types of fuel taking into account the role of cargo transportation by sea. Directions for solving these problems without a significant impact on the cost of cargo transportation are proposed, consisting of the selection of raw materials, their preliminary processing, the use of the latest processing technologies and compounding of finished commercial products. The selection of raw materials consists of determining the types and grades of raw materials that are provided with sufficient industrial reserves for the implementation of the selected technology and are characterized by a certain level of quality, for example, low (<0.5 %) sulfur content. The use of the latest technologies consists of thermal (cracking, pyrolysis) and thermocatalytic (catalytic cracking and pyrolysis, hydrotreating and hydrocracking) processes for obtaining fuel with a low sulfur content from hydrocarbon raw materials. Fuel compounding occurs with components with a significantly lower sulfur content. For this, various petroleum distillates, commercial fuels, some liquid products of coal gasification, as well as products of thermal degradation of polymer raw materials can be used. In practice, in the production of marine fuel with a low sulfur content, the most effective combination of several directions in a single technological chain: "selection of raw materials - the latest technologies" or "selection of raw materials - the latest technologies - compounding". Considering the above, it is shown that at present one of the most promising technological processes for the production of motor fuels, in particular marine ones, in Ukraine catalytic pyrolysis of secondary polymer raw materials on zeolites can be considered. Key words: marine fuel, sulfur, shipping, environmental requirements, polymers, pyrolysis, catalyst, petroleum distillates, coal gasification products. Corresponding author: A.B. Grigorov, e-mail: grigorovandrey@ukr.net
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含硫量低的船用燃料,在乌克兰有生产前景。
本文考虑了船舶燃料使用的主要全球趋势。乌克兰商船队目前广泛使用的F-5和F-12级船用燃料油有必要替换为含硫量低的新型燃料,如船用燃料油(MGO)或低硫船用燃料油(LS-MGO)。主要问题是有特点的,而考虑到海上货物运输的作用,这些问题在向新型燃料过渡期间可能出现。提出了在不显著影响货物运输成本的情况下解决这些问题的方向,包括原材料的选择、原材料的初步加工、最新加工技术的使用和成品的复合。原材料的选择包括确定原材料的类型和等级,这些原材料为所选技术的实施提供了足够的工业储备,并具有一定的质量水平,例如,低(< 0.5%)硫含量。最新技术的使用包括热(裂化、热解)和热催化(催化裂化、热解、加氢处理和加氢裂化)工艺,以从碳氢化合物原料中获得低硫含量的燃料。燃料复合发生在含硫量明显较低的组分中。为此,可以使用各种石油馏分油、商业燃料、煤气化的一些液体产品以及聚合物原料的热降解产品。在实践中,在低硫含量船用燃料的生产中,最有效的是在单一的技术链中结合几个方向:“选择原料-最新技术”或“选择原料-最新技术-复合”。综上所述,目前在乌克兰,可以考虑在沸石上催化裂解二次聚合物原料,这是生产汽车燃料,特别是船用燃料最有前途的技术之一。关键词:船用燃料,硫,船舶,环境要求,聚合物,热解,催化剂,石油馏分,煤气化产品通讯作者:A.B. Grigorov, e-mail: grigorovandrey@ukr.net
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