Predicting the Permeability and Relative Permeability of Concrete

Lionel Ecay, D. Grégoire, G. Pijaudier-Cabot
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Abstract

France has today reassessed the safety level of its power plants due to the Fukushima incident. The duration of the cooling system breakdown urged the industry to consider a much longer worst case scenario than was done before. The time frame for the ’severe’ accident subsequently went up from 24h to two weeks. This, in turn, called for an extensive study of creep and vapour transport issues that had previously been left aside. This was the objective of the MACENA project, which aims at evaluating the tightness of a containment vessel under extreme conditions, namely a 5 bar water vapour pressure and 180C temperature during two weeks. Among the scientific issues involved in this problem, the intrinsic permeability of concrete, its relative permeability to vapour and to water and their subsequent evolution upon damage are the subject of this contribution. Our analysis starts from the work of Khaddour et al. on the impact of damage on both intrinsic and apparent permeability with the help of a random hierarchical model based on the pore size distribution of the material. This model yielded good results in terms of the evolution of permeability with damage. Here, we extend this model to the description of multiphase fluid flow. Modifications of the above-mentioned random hierarchical model involve a set of rules that capture the effect of condensation as described by Kelvin’s law. In addition, the capillary assembling process is modified in order to better account for the influence of capillaries of very small diameter, which had no importance on the prediction of the intrinsic permeability but have a strong influence on the relative permeability to vapour. Segments of capillaries of small diameter are redistributed in downstream ends of the bundle according to a probability distribution that has the same shape as the pore size distribution. The extended model is shown to provide rather accurate prediction of relative permeability for a wide range of geomaterials (from mortar to tight and permeable rocks).
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混凝土渗透性和相对渗透性的预测
由于福岛核事故,法国今天重新评估了其核电站的安全水平。冷却系统故障的持续时间促使业界考虑比以往更长时间的最坏情况。“严重”事故的时间框架随后从24小时延长到两周。这反过来又要求对蠕变和蒸气输送问题进行广泛的研究,而这些问题以前被搁置一边。这就是MACENA项目的目标,该项目旨在评估安全壳在极端条件下的密封性,即在两周内5巴的水蒸气压力和180摄氏度的温度下。在这个问题所涉及的科学问题中,混凝土的内在渗透性,它对蒸汽和水的相对渗透性以及它们在损坏后的后续演变是这一贡献的主题。我们的分析从Khaddour等人的工作开始,借助基于材料孔径分布的随机分层模型,研究损伤对固有渗透率和表观渗透率的影响。该模型在渗透率随损伤的演化方面取得了较好的结果。在这里,我们将该模型扩展到多相流体流动的描述。对上述随机分层模型的修改涉及一组规则,这些规则捕获了由开尔文定律描述的冷凝效应。此外,为了更好地考虑非常小直径的毛细血管的影响,对毛细管组装过程进行了修改,这些毛细血管对固有渗透率的预测不重要,但对相对蒸汽渗透率有很大影响。小直径的毛细血管片段在束的下游端按照与孔径分布形状相同的概率分布重新分布。该扩展模型对各种岩土材料(从砂浆到致密和透水性岩石)的相对渗透率提供了相当准确的预测。
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