Synthesis and characterization of Nano ashes from different waste materials and their effects on the compressive strength of sustainable concrete: A systematic review

H. Ahmed, Dalya F. Ibrahim, Rozhno Mustafa, Rabar H. Faraj
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Abstract

Nanotechnology can be regarded as one of the new research fields having novelty and important applications that recently gained attention, especially during the last twenty years. The implementation of nanotechnology produces materials with novel characteristics and recently many works were conducted to include nanoparticles (NPs) in cement-based materials to improve performance and manufacture concrete with better behavior under different mechanical and environmental conditions. Previous studies demonstrated that different waste ashes such as, fly ash, cement kiln dust, palm oil fuel ash, eggshell ash, Metakaolin, and waste ceramic ash can be efficiently converted to sustainable nano ashes. The chemical and physical properties of the produced nano ashes were significantly different from their parent ashes. Therefore, the concrete produced with these nano ashes had superior properties compared to the normal concrete made with traditional waste ashes. This paper presents a systematic overview of the synthesis and characterization of different nano ashes and their impacts on the performance of concrete mixtures. Based on the results from the comprehensive review, it was illustrated that the specific surface to volume ratio was considerably increased by converting the ashes to nano ashes, thus the properties of concrete were also improved. Moreover, due to the higher specific surface area of nano ashes and their reaction with undesirable C-H which is present in the cement paste matrix to produce additional C-S-H, the microstructure of concrete was considerably enhanced.
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不同废弃物纳米灰的合成、表征及其对可持续混凝土抗压强度的影响
纳米技术是近年来特别是近二十年来受到广泛关注的具有新颖性和重要应用价值的新兴研究领域之一。纳米技术的实施产生了具有新特性的材料,最近进行了许多工作,将纳米颗粒(NPs)加入水泥基材料中,以提高性能,并制造出在不同机械和环境条件下性能更好的混凝土。以往的研究表明,粉煤灰、水泥窑灰、棕榈油燃料灰、蛋壳灰、偏高岭土、废陶瓷灰等不同的废灰都可以有效地转化为可持续的纳米灰。制备的纳米灰的化学和物理性质与母灰有明显不同。因此,与传统废灰制成的普通混凝土相比,用这些纳米灰制成的混凝土具有优越的性能。本文系统地综述了不同纳米灰的合成、表征及其对混凝土混合料性能的影响。综合评价结果表明,将粉煤灰转化为纳米粉煤灰可显著提高混凝土的比表面积与体积比,从而改善混凝土的性能。此外,由于纳米灰具有较高的比表面积,并且与水泥浆体基体中存在的不需要的C-S-H发生反应,产生额外的C-S-H,从而大大增强了混凝土的微观结构。
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