Space Charge Behavior in AC Electrically Aged Low-Density Polyethylene Films

Zixia Cheng, Jin-Rui Shi, Ling Zhang, Yuanxiang Zhou, Zekai Lu, Shaowei Guo
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Abstract

In order to study the effect of AC aging on space charge characteristics of low-density polyethylene (LDPE) films, an AC electric field of 50 kV/mm (peak value) was adopted for the accelerated aging test and space charge measurements of AC aged LDPE films were carried out subsequently. The results show that no significant space charge accumulation in the LDPE samples aged under a 50 kV/mm AC electric field. It can be seen that a significant positive space charge accumulation occurs inside the sample, when DC electric fields were applied to the AC aged LDPE samples. The long-term AC aging also causes more and deeper cracks on the surface of LDPE samples. Moreover, AC aging promotes the oxidation reaction of LDPE. The longer the aging time, the higher the degree of oxidation. On this basis, the probable relationship between space charge characteristics and material physicochemical properties of LDPE during AC electrical aging is clarified.
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交流电老化低密度聚乙烯薄膜的空间电荷行为
为了研究交流老化对低密度聚乙烯(LDPE)薄膜空间电荷特性的影响,采用50 kV/mm(峰值)的交流电场进行加速老化试验,随后对交流老化LDPE薄膜进行空间电荷测量。结果表明:在50kv /mm的交流电场作用下,LDPE样品中没有明显的空间电荷积累;可以看出,当直流电场作用于交流老化的LDPE样品时,样品内部出现了明显的正空间电荷积累。长期的交流老化也会使LDPE试样表面产生更多更深的裂纹。交流老化促进了LDPE的氧化反应。老化时间越长,氧化程度越高。在此基础上,阐明了LDPE在交流电老化过程中空间电荷特性与材料理化性质之间的可能关系。
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