Physicochemical and Performance Assessment of Clay Based Refractory Bricks for Incinerator Application

Ezekiel Iliya, Amoko Oluwole
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Abstract

Refractories bricks’ excellent thermomechanical and chemical resistant features makes it invaluable materials in modular incinerator ˃ 1000 °C applications. In this research, suitable physicochemical and performance evaluation were employed using X-Ray Fluorescence (XRF), dimensional property assessment, linear shrinkage and water absorption analysis. The samples were sourced from Auchi (ARB1), Afowa (ARB2), Ayogwiri (ARB3), Aviele (ARB4) and Agbede (ARB5) clay minerals deposit in Edo North, Edo State, Nigeria. Then green compact samples were fired into dense phase. The result from the XRF study revealed a generally established composition of ARB1 clay mineral of SiO2: 44.34%, Al2O3: 36.36% and others. ARB2 clay mineral of SiO2: 41.78%, Al2O3: 39.62% and others. ARB3 clay mineral of SiO2: 45.04%, Al2O3: 34.01% and others. ARB4 clay mineral of SiO2: 40.12%, Al2O3: 38.96% and others. ARB5 clay mineral of SiO2: 47.03%, Al2O3: 34.52% and others. The elemental composition of ARB1-5 revealed a similar trend of alumina and silica content to high-Al2O3 bricks (SiO2: 45.0 – 56.0%, Al2O3: 39.0 – 48.0% and others) and commercial clay bricks (SiO2: 48.0%, Al2O3: 36.96% and others) respectively. An average lower percentage error ERL, ERW, and ERH of ARB1 samples 0.148, 0.248 and 0.28% were recorded respectively. The average linear shrinkage and water absorption analysis of 9.91 and 4.71% demonstrated a potential for high elasticity of modulus. The overall data from this research shows that ARB1-5 bricks can find use in incinerator and high temperature applications.
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焚烧炉用粘土基耐火砖的理化性能评价
耐火砖优异的耐热性和耐化学性使其成为模块化焚烧炉1000°C应用的宝贵材料。在本研究中,采用x射线荧光(XRF)、尺寸性能评估、线性收缩率和吸水率分析等方法对其进行了适当的理化和性能评价。样品来自尼日利亚江户州北江户的Auchi (ARB1)、Afowa (ARB2)、Ayogwiri (ARB3)、Aviele (ARB4)和Agbede (ARB5)粘土矿物矿床。然后将绿色致密样品烧制成致密相。XRF分析结果表明,ARB1粘土矿物组成大致为SiO2: 44.34%, Al2O3: 36.36%等。ARB2粘土矿物SiO2: 41.78%, Al2O3: 39.62%等。ARB3粘土矿物SiO2: 45.04%, Al2O3: 34.01%等。ARB4粘土矿物SiO2: 40.12%, Al2O3: 38.96%等。ARB5粘土矿物SiO2: 47.03%, Al2O3: 34.52%等。ARB1-5的元素组成显示出与高Al2O3砖(SiO2: 45.0 ~ 56.0%, Al2O3: 39.0 ~ 48.0%等)和商业粘土砖(SiO2: 48.0%, Al2O3: 36.96%等)相似的氧化铝和二氧化硅含量趋势。ARB1样品的平均误差百分比ERL、ERW和ERH分别为0.148、0.248和0.28%。平均线收缩率和吸水率分别为9.91%和4.71%,具有高弹性模量的潜力。本研究的总体数据表明,ARB1-5砖可用于焚化炉和高温应用。
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