Modeling and calculations of parameters of the joint treatment of organic contaminations (OC) and nitrogen (N) compounds in bioreactors with using of the fixed biocenosis (biofilm)

O. Oliynyk, Sergiy V. Telyma, Y. Kalugin, Yevheniy O. Oliynyk
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Abstract

The mathematical models and the parameter calculations of the simultaneous waste water treatment from the organic contaminants and ammonium nitrogen compounds in the bioreactors-aerotanks with additional fixed biocenosis as a biofilm in their volume are proposed. The questions connected with heterogeneous structure of biofilm from different bacteria and the substantiation of the balance equations system with kinetic reactions for following their realization which are describing of the simultaneous removing organic contaminations (OC) and nitrogen (N) in biofilm taking into account on the oxygen regime O2 are considered. Detailed analysis of aerotank operation with additional fixed biocenosis shown about the possibility of creation of the new conditions for simultaneous removing of the OC and nitrogen by the suspended and fixed biocenosis. At the same time the arrangement of the aerotank-mixture from the three sections where the simultaneous treatment have a place is recommended taking into account on the theoretical substantiation of these sections in one reactor. It is shown that on the different loads the complex heterogeneous structure of the biofilm is formed which consist of from different bacteria. So near the biofilm surface it consists of the heterotrophs during the removing of OC and at during of removing of nitrogen from the autotrophs. At the same time more active heterotrophs may to grow as in anaerobic as in anoxic conditions and the processes that have a place in the biofilm at the simultaneous treatment are connected with the growing of the competition between the heterotrophs and autotrophs in the fight to oxygen. Heterotrophy that are situated are near surface of the biofilm are using of more oxygen than autotrophy that are in the lower part of one. As a result of realization of the created models taking into account on the influence of the different factors on the simultaneous waste water treatment from OC and N processes the recommendations to parameter calculations are proposed. Besides of the boundary conditions of necessary bacteria presence at which the simultaneous removing of the OC and N are occurred and at which conditions some of substrates will limit the waste water treatment processes are determined.
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固定式生物膜联合处理生物反应器中有机污染物(OC)和氮(N)的建模与参数计算
提出了在体积中附加固定菌体作为生物膜的生物反应器-气气罐中同时处理有机污染物和铵态氮化合物的数学模型和参数计算。讨论了不同细菌生物膜的非均质结构问题,以及在氧态O2条件下描述生物膜中有机污染物(OC)和氮(N)同时去除的动力学反应平衡方程组的建立。详细分析了附加的固定生物藻的气罐操作,显示了通过悬浮和固定生物藻同时去除OC和氮的新条件的可能性。同时,考虑到在一个反应器中同时处理的三个区段的理论依据,建议在三个区段中同时处理的混合气罐的布置。结果表明,在不同的负荷下,由不同的细菌组成的生物膜形成了复杂的异质结构。所以在生物膜表面附近它由异养生物组成在去除OC的过程中在去除自养生物中的氮的过程中。同时,在厌氧和缺氧条件下,更活跃的异养生物可能会生长,同时在生物膜中占有一席之地的过程与异养生物和自养生物争夺氧气的竞争的增长有关。位于生物膜表面附近的异养生物比位于生物膜下部的自养生物消耗更多的氧气。考虑到不同因素对OC和N工艺同时处理废水的影响,所建立的模型得以实现,并对参数计算提出了建议。除了确定同时去除OC和N的必要细菌存在的边界条件外,还确定了一些底物将限制废水处理过程的条件。
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