Influence of orientational phase transition in conductivity of fullerene-iodine films

A. Berdinsky, Y. Shevtsov, A. V. Okotrub, D. Fink, L. T. Chadderton
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Abstract

The synthesis and research of intercalated fullerene are greatly significant in understanding for this new molecular modification of carbon. Here we report the results of conductive properties of fullerene-iodine compound films. It is found that there are strong changes in the temperature dependence of the conductivity in range of 240-250 K which can be concerned with orientational phase transition of fullerene molecule. It should be noted that the value of changes of conductivity much more strong than in pure fullerene films.
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取向相变对富勒烯-碘薄膜电导率的影响
嵌层富勒烯的合成和研究对于理解这种新型的碳分子修饰具有重要意义。本文报道了富勒烯-碘化合物薄膜导电性能的研究结果。发现在240 ~ 250 K范围内,电导率的温度依赖性有很大的变化,这可能与富勒烯分子的取向相变有关。值得注意的是,电导率的变化值比纯富勒烯薄膜强得多。
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