Preparation and thermoelectric properties of grain aligned (Ca,Bi)/sub 3/Co/sub 4/O/sub 9/ ceramics

I. Matsubara, R. Funahashi, T. Takeuchi, Y. Zhou
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引用次数: 5

Abstract

Effects of sintering process on the thermoelectric properties of (Ca,Bi)/sub 3/Co/sub 4/O/sub 9/ ceramics have been investigated. We have prepared (Ca, Bi)/sub 3/Co/sub 4/O/sub 9/ bulk materials using the methods of spark plasma sintering (SPS), hot pressing (HP), and a combination of them. Power factors of the SPS and HP samples at 700/spl deg/C are 4.2/spl times/10/sup -4/ Wm/sup -1/ K/sup -2/ and 4.5/spl times/10/sup -4/ Wm/sup -1/ K/sup -2/, respectively. The combination of SPS and HP enables bulk ceramics (SPS-HP) to be high density, grain alignment, and low resistivity without any degradation of the thermoelectric power. The power factor and figure of merit of the SPS-HP sample attain to 5.7/spl times/10/sup -4/ Wm/sup -1/ K/sup -2/ and ZT=0.29 at 700/spl deg/C, respectively.
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晶粒排列(Ca,Bi)/sub 3/Co/sub 4/O/sub 9/陶瓷的制备及其热电性能
研究了烧结工艺对(Ca,Bi)/sub 3/Co/sub 4/O/sub 9/陶瓷热电性能的影响。我们采用火花等离子烧结(SPS)、热压(HP)和两者结合的方法制备了(Ca, Bi)/sub 3/Co/sub 4/O/sub 9/块状材料。在700/spl℃时,SPS和HP样品的功率因数分别为4.2/spl倍/10/sup -4/ Wm/sup -1/ K/sup -2/和4.5/spl倍/10/sup -4/ Wm/sup -1/ K/sup -2/。SPS和HP的结合使体陶瓷(SPS-HP)具有高密度、晶粒排列和低电阻率的特点,而不会降低热电功率。在700/spl℃时,SPS-HP样品的功率因数和品质系数分别达到5.7/spl times/10/sup -4/ Wm/sup -1/ K/sup -2/和ZT=0.29。
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