GASEOUS FUEL OBTAINING VIA FERMENTATION OF ORGANIC LANDFILL WASTE

V. Hovorukha, O. Havryliuk, G. Gladka, Bida Iryna, Y. Danko, O. Shabliy, O. Tashyrev
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Abstract

Fossil carbon-containing fuel is currently one of the most common in industry and economy. The rapid depletion of reserves of this fuel makes it necessary to search for the alternative one. Landfills are a place where methane is spontaneously synthesized due to the decay of organic waste. Controlled and regulated fermentation of the landfill organics can provide biomethane as well as environmental bioremediation. The aim of the work was to study the patterns of methane fermentation of multi component organic waste and optimize the process to increase the efficiency of biomethane synthesis and waste decomposition. Colorimetric and potentiometric methods were used for pH and Eh measurement. Volumetric and chromatographic methods were applied to control volume and composition of synthesized gas. Fermentation parameters were calculated with the use of mathematical and statistical ones. The achievement of high efficiency of methane fermentation of organic waste due to the process regulation was shown. The modeling of unregulated fermentation of organic waste in landfills showed low efficiency of the process. It took 69 days. Weight of waste decreased only 5 times. Hydrogen yield was 5 L/kg of waste. Methane was not synthesized. The regular mass transfer, regulation of the process and waste grinding showed the greatest efficiency. Weight of waste decreased 20 times during only 14 days. Hydrogen yield was 27 L/kg, methane yield was 12 L/kg of waste. Thus, the absence of regulation caused long term decay of waste. The high efficiency is achieved due to regulation of the fermentation process. The results will serve as a basis for the development of industrial biotechnology for the utilization of organic waste to reduce the volume of existing landfills and produce methane energy. This will further allow bioremediation of contaminated areas, obtaining an alternative to fossil fuel biomethane.
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通过有机垃圾填埋场垃圾发酵获得的气体燃料
含碳化石燃料是目前工业和经济中最常用的燃料之一。这种燃料储量的迅速枯竭使得有必要寻找替代燃料。垃圾填埋场是由于有机废物的腐烂而自发合成甲烷的地方。垃圾填埋场有机物的可控发酵不仅可以提供生物甲烷,还可以对环境进行生物修复。本研究旨在研究多组分有机废弃物的甲烷发酵规律,并对其进行工艺优化,以提高生物甲烷合成和废弃物分解效率。pH和Eh的测定采用比色法和电位法。采用体积法和色谱法控制合成气的体积和组成。利用数理统计法计算发酵参数。通过工艺调控,实现了有机废弃物甲烷高效发酵。通过对垃圾填埋场有机废弃物无调节发酵过程的模拟,发现该过程效率较低。整个过程花了69天。废物重量只减少了5倍。产氢量为5 L/kg废弃物。甲烷不是合成的。有规律的传质、有规律的工艺、有规律的废磨效率最高。仅在14天内,废物重量就减少了20倍。产氢量为27 L/kg,甲烷量为12 L/kg。因此,缺乏监管导致了废物的长期衰变。由于发酵过程的调节,实现了高效率。研究结果将作为开发利用有机废物的工业生物技术的基础,以减少现有垃圾填埋场的体积并产生甲烷能源。这将进一步允许污染地区的生物修复,获得化石燃料生物甲烷的替代品。
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