Deaeration, pH shift, and surface disruption effects on the corrosion of modular THR alloys

V. Bucalo, K. Bundy
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Abstract

Recent clinical retrieval studies have shown that extensive attack often occurs in modular total hip replacements (THR's). Proposed causes for the degradation of these implants include galvanic, crevice, and fretting corrosion, as well as combinations of these effects. The research described here is part of an ongoing study to determine the mechanism or mechanisms behind these high rates of attack. DC electrochemical techniques have been employed to conduct short, term studies related to device corrosion and fretting. The results suggest that fretting accelerated crevice corrosion is sufficient but not necessary for severe attack of modular THR's. Crevice conditions alone may cause the attack, if the pH and p/sub O2/ levels decline sufficiently far.
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脱氧、pH值变化和表面破坏对模块化THR合金腐蚀的影响
最近的临床检索研究表明,广泛的攻击经常发生在模块化全髋关节置换术(THR’s)。这些植入物退化的原因包括电偶、缝隙和微动腐蚀,以及这些影响的组合。这里描述的研究是一项正在进行的研究的一部分,该研究旨在确定这些高发病率背后的机制。直流电化学技术已被用于进行与器件腐蚀和微动有关的短期和长期研究。结果表明,微动加速裂缝腐蚀是充分的,但不是模块化THR严重攻击的必要条件。如果pH值和p/sub O2/水平下降得足够远,仅裂缝条件就可能引起攻击。
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