Synthesis of polar copolymers by the process of emulsion via free radicals (FRP)

Luis Mario Magaña-Maldonado, D. Contreras-López
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Abstract

At present, the polymer industry has gained increasing importance due to the versatility of its properties, as well as the impact they have on the environment. The present investigation provides the determination of optimal operating conditions for the polymerization of styrene and vinyl propionate in a Batch reactor, as well as the copolymerization of styrene with propionate monomers by the process of emulsion via free radicals, allowing to observe the variations with respect to Reaction yields and molecular weights. Another important factor is the activation of the initiator so that the polymerization process begins within each of the micelles. Likewise, it was found that, in the copolymerizations, there are considerable variations with respect to reaction yields and molecular weights as the concentrations are modified. In addition, it was found that there are higher yields in styrene polymerizations per solution than emulsion.
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自由基乳液法合成极性共聚物(FRP)
目前,聚合物工业由于其特性的多功能性以及对环境的影响而变得越来越重要。本研究提供了在间歇式反应器中聚合苯乙烯和丙酸乙烯的最佳操作条件的确定,以及苯乙烯与丙酸单体通过自由基的乳液过程的共聚,允许观察反应产率和分子量的变化。另一个重要因素是引发剂的活化,使聚合过程在每个胶束内开始。同样地,我们发现,在共聚反应中,随着浓度的改变,反应产率和分子量也有相当大的变化。此外,还发现溶液中苯乙烯聚合的产率高于乳液。
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