Optical detection of the corrosion of stainless steel 304L exposed to lithium bromide aqueous solution at 70°C

J. Castrellón-Uribe, A. Trujillo-Estrada, C. Cuevas-Arteaga
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Abstract

We report a new method based on the ratio of the optical transmittance to monitoring processes of corrosion in stainless steel 304L immersed in a aqueous solution of lithium bromide at 50% wt, at 70°C. The change of the optical transmittance that is measured in the solution contaminated, is related to the physical degradation of the samples of stainless steel. We determine that the optic spectral-interval with more sensitivity to the corrosion products-accumulation, dissolved in the lithium bromide solution is of [450 nm - 750 nm]. A laser at 632 nm is utilized to detect the corrosion oxides-accumulation dissolved in the lithium bromide solution for 20 days. The slope of the change ratio of the optical power of transmittance is of 31X10-3/hour for 480 hours of exposition. Finally, the experimental results that we have presented, show that this optical technique represents an alternative in the detection of the corrosion without establishing physical contact with the sample.
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光学检测304L不锈钢暴露于70℃溴化锂水溶液中的腐蚀情况
我们报告了一种基于光学透射率的新方法,以监测不锈钢304L在溴化锂水溶液中浸在50% wt, 70°C的腐蚀过程。在被污染的溶液中测量的透光率的变化与不锈钢样品的物理降解有关。我们确定了对溴化锂溶液中腐蚀产物积累更敏感的光学光谱区间为[450 nm - 750 nm]。利用632 nm激光检测溶解在溴化锂溶液中的腐蚀氧化物积累,持续20天。照射480小时时,透射光功率变化率斜率为31X10-3/h。最后,我们提出的实验结果表明,这种光学技术代表了在不与样品建立物理接触的情况下检测腐蚀的替代方法。
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