Low temperature snap cure thermoset adhesives with good worklife

S. Gillissen, E. Nelis, G. van Wuytswinkel, M. de Pater, Chih-Min Cheng, V. Buffa, W. O'hara, B. Xia, Jayesh Shah
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引用次数: 5

Abstract

A break-through adhesive chemistry has been developed that achieves cure in seconds at temperatures below 110°C. These adhesives enable low cost RFID tag construction with low temperature substrates at extremely high assembly speed. Assemblies that require electrically conductive or non-conductive adhesives can benefit from this innovation. The cure speed of isotropic conductive paste (ICP) adhesive is demonstrated by measuring dynamic conductivity development during the heating process. Rheological stability at room temperature persists for days. The impact of rheological behavior on high speed processing is discussed. Silver ink based antenna and simulated die strap are used as test vehicles for processing and reliability tests. The integrity of the assembly is shown using a mandrel bend test to simulate downstream processing such as converting and printing. Together with a proprietary thermal radiation cure method, assembly speeds up to 300 feet/minute are achievable. The electrical stability of these bend-tested tags were evaluated in air to air thermal shock (-40°C to 80°C) and 85°C/85%RH conditions and found to be stable. The reliability results are presented and the challenge of high speed reel-to-reel processing are also discussed based on an isotropic conductive adhesive approach. This paper discusses these results and presents an adhesive technology that enables low cost RFID tag assembly.
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低温快速固化热固性粘合剂,具有良好的工作寿命
一种突破性的粘合剂化学技术已经开发出来,可以在低于110°C的温度下在几秒钟内实现固化。这些粘合剂使低温基板的低成本RFID标签结构具有极高的组装速度。需要导电或非导电粘合剂的组件可以从这项创新中受益。通过测量各向同性导电浆料(ICP)在加热过程中的动态电导率发展,证明了其固化速度。室温下的流变稳定性可维持数天。讨论了流变特性对高速加工的影响。以银墨水基天线和模拟模带为试验载体,进行工艺和可靠性试验。使用芯轴弯曲测试来模拟下游加工,如转换和打印,以显示组件的完整性。结合专有的热辐射固化方法,可实现高达300英尺/分钟的组装速度。在空气对空气热冲击(-40°C至80°C)和85°C/85%RH条件下评估这些弯曲测试标签的电稳定性,发现是稳定的。给出了可靠性结果,并讨论了基于各向同性导电胶方法的高速卷对卷加工所面临的挑战。本文讨论了这些结果,并提出了一种粘合技术,使低成本的RFID标签组装。
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