Effect of Fe on hydrogenation and dehydrogenation of Sm(CobalFexCu0.053Zr0.02)7.84(x=0.2,0.3,0.4,0.5) alloys

M. Li, Z. Liu, L. Lei, Z. Xue, S. He, R. Chen, D. Lee, X. Liu, A. Yan
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引用次数: 1

Abstract

Hydrogen decrepitation as a highly efficient and excellent crushing method is widely used in the preparation of NdFeB magnets. However, this method still exist many difficulties in the industrial preparation for 2:17 type SmCo alloys owing to high hydrogen pressure. Our previous work has reported 2:17 type SmCo alloys occur HD at room temperature and hydrogen pressure of 0.3 MPa and has shown that Fe atom improved hydrogenation decrepitation ability of alloys by improving hydrogen-absorbing ability of 1:7 phase. But the mechanism that Fe improve hydrogen-absorbing ability of the 1:7 phase still need further study. In addition, subsequent degassing behaviour of alloys have been studied by using DSC.
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Fe对Sm(CobalFexCu0.053Zr0.02)7.84(x=0.2,0.3,0.4,0.5)合金加氢和脱氢的影响
氢衰法作为一种高效、优良的破碎方法,广泛应用于钕铁硼磁体的制备。然而,由于氢气压力高,这种方法在工业制备2:17型SmCo合金时仍存在许多困难。我们之前的工作报道了2:17型SmCo合金在室温和0.3 MPa的氢压下发生HD,并表明Fe原子通过提高1:7相的吸氢能力来提高合金的氢化破蚀能力。但Fe提高1:7相吸氢能力的机理还有待进一步研究。此外,用DSC研究了合金的后续脱气行为。
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