Strain-Sensing Properties of Chitosan-Based Film Composites

V. A. Kuznetsov, Dmitry I. Gapich, A. A. Fedorov, B. Kholkhoev, A. S. Buinov, V. F. Burdukovskii
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Abstract

The paper is devoted to strain-sensing properties of biopolymer composite film materials based on chitosan matrix with few-layered graphene as electrically conductive filler particles. The composite films were made by flow-coating method of colloidal dispersions of few-layered graphene in solution of chitosan in water and lactic acid with polyvinylpyrrolidone or pluronic F108 as surfactants. The experimental samples about 70–100 µm in thickness were made with few-layered graphene content of 3% and 4% (wt.) for the composites with polyvinylpyrrolidone and 2 %, 3 %, 4 % and 5% (wt.) with pluronic F108. Electrical resistivity changed from 0.016 to 1300 Ohm-m depending on surfactant and few-layered graphene content. The samples were shown to have strain-sensing properties, the strain gauge factor to be from 1.3 to 5.7 depending on the filler content and surfactant used. The strain-sensing properties were studied with beams of uniform strength (in bending), the composites bonded to them with cyanoacrylate glue. The composites are perspective as strain gauges for health monitoring due to their biocompatibility.
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壳聚糖基薄膜复合材料的应变传感性能
研究了以壳聚糖为基体,以少层石墨烯为导电填料的生物高分子复合薄膜材料的应变传感性能。以聚乙烯吡罗烷酮或pluronic F108为表面活性剂,将单层石墨烯胶体分散体在壳聚糖水溶液和乳酸溶液中流动涂覆制备复合薄膜。聚乙烯吡咯烷酮和pluronic F108分别以3%和4% (wt.)的石墨烯含量和2%、3%、4%和5% (wt.)的石墨烯含量制备了厚度约为70-100µm的实验样品。电阻率变化范围为0.016 ~ 1300欧姆,取决于表面活性剂和少层石墨烯含量。结果表明,样品具有应变传感性能,应变计系数根据填料含量和表面活性剂的不同在1.3 ~ 5.7之间。在弯曲强度均匀的梁上,用氰基丙烯酸酯胶粘接复合材料,研究了复合材料的应变传感性能。该复合材料具有良好的生物相容性,可作为健康监测的应变片。
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